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Phase Transitions at Internal Interfaces

Published online by Cambridge University Press:  25 February 2011

Craig Rottman*
Affiliation:
North Dakota State University, Department of Physics, Fargo, ND 58105–5566
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Abstract

Interfaces often undergo phase transitions even though nothing special is happening to the bulk solid. These transitions are possible in any internal interface, such as a grain boundary, an interphase boundary, a stacking fault, or an antiphase boundary. As for bulk solids, interface transitions may be defined from a thermodynamic point of view. When distinct interfacial phases coexist, interfacial phase diagrams are useful in visualizing thermodynamic data. Various classes of these transitions will be discussed in general and then illustrated with examples from recent work on models and experimental systems.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

1. Gibbs, J.W., Collected Works (Yale Univ. Press, New Haven, 1957), Vol. 1.Google Scholar
2. Rottman, C., J. Physique Colloq. 49 (C5), 313 (1988).Google Scholar
3. Ordering in Two Dimensions, edited by Sinha, S.K. (North-Holland, New York, 1980);Google Scholar
Zangwill, A., Physics at Surfaces (Cambridge Univ. Press, Cambridge, 1988).CrossRefGoogle Scholar
4. Griffiths, R.B., in Phase Transitions in Surface Films, edited by Dash, J.G. and Ruvalds, J. (Plenum, New York, 1980), pp. 127.Google Scholar
5. Cahn, J.W., in Interfacial Segregation, edited by Johnson, W.C. and Blakely, J.M. (ASM, Metals Park, OH, 1979), pp. 323.Google Scholar
6. Cahn, J.W., J. Physique Colloq. 43 (C6), 199 (1982).Google Scholar
7. Wolf, D., J. Physique Colloq. 46 (C4), 197 (1985);Google Scholar
Merkle, K.L. and Wolf, D., MRS Bulletin 15 (9), 42 (1990).Google Scholar
8. Cabrera, N., in Symposium on Properties of Surfaces (ASTM, Philadelphia, PA, 1963), pp 2431;CrossRefGoogle Scholar
9. Andreev, A.F., Sov. Phys. JETP 53, 1063 (1981);Google Scholar
Rottman, C. and Wortis, M., Phys. Rep. 103, 59 (1984).Google Scholar
10. Rottman, C., in Structure/Property Relationships for Metal/Metal Interfaces, edited by Romig, A.D., Fowler, D.E., and Bristowe, P.D. (Mater. Res. Soc. Proc. 229, Pittsburgh, PA (1991); J. Materials Res. (to be published).Google Scholar
11. Goodhew, P.J., Tan, T.Y., and Balluffi, R.W., Acta Metall. 26, 557 (1978);Google Scholar
Eastman, J.E. and Sass, S.L., J. Amer. Ceram. Soc. 69, 753 (1986).CrossRefGoogle Scholar
12. Hackney, S.A., Scripta Metall. Mat. 25, 1023 (1991).Google Scholar
13. Finel, A., Mazauric, V., and Ducastelle, F., J. Physique Colloq. 51 (C1), 139 (1990); Phys. Rev. Lett. 65, 1016 (1990).Google Scholar
14. Kikuchi, R. and Cahn, J.W., Acta Metall. 27, 1337 (1979).CrossRefGoogle Scholar
15. Pandit, R., Schick, M., and Wortis, M., Phys. Rev. B 26, 5112 (1982).Google Scholar
16. Rabkin, E.I., Semenov, V.N., Shvindlerman, L.S., and Straumal, B.B., Acta Metall. Mater. 39, 627 (1991).CrossRefGoogle Scholar