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Optical And Electrical Properties Of Doped Polysilanes

Published online by Cambridge University Press:  16 February 2011

M. Kakimoto ,
H. Ueno ,
H. Kojima ,
Y. Yamaguchi  and
A. Nishimura
M. Kakimoto
Affiliation:
Osaka R&D Laboratories, Sumitomo Electric Industries, Ltd., 1–1–3 Shimaya, Konohana-ku, Osaka 554, JAPAN
H. Ueno
Affiliation:
Osaka R&D Laboratories, Sumitomo Electric Industries, Ltd., 1–1–3 Shimaya, Konohana-ku, Osaka 554, JAPAN
H. Kojima
Affiliation:
Osaka R&D Laboratories, Sumitomo Electric Industries, Ltd., 1–1–3 Shimaya, Konohana-ku, Osaka 554, JAPAN
Y. Yamaguchi
Affiliation:
Osaka R&D Laboratories, Sumitomo Electric Industries, Ltd., 1–1–3 Shimaya, Konohana-ku, Osaka 554, JAPAN
A. Nishimura
Affiliation:
Osaka R&D Laboratories, Sumitomo Electric Industries, Ltd., 1–1–3 Shimaya, Konohana-ku, Osaka 554, JAPAN
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Abstract

The doping effects on optical and electrical properties of polysilanes have been investigated by in-situ Measurement. An optical absorption associated with σ–σ* transition was observed near 330 nm for polymethylphenylsilane. By iodine doping, a new absorption was observed at the longer wavelength around 420 nm, which should originate from the charge transfer between dopant and Σ-conjugated system. Similar spectral changes have also been observed for most of investigated linear polysilanes.

Furthermore, we have found drastic spectral change upon iodine doping into polysilane with p-N,N-dimethyIaminophenyI substituent. It has very strong absorption up to 700 nm. It Might originate from a strong interaction between the substituent and iodine. At the same time, Σ-conjugation Might also play a significant role on doping into this system.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 328: Symposium Q – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1993 , 267
Copyright
Copyright © Materials Research Society 1994

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References

REFERENCES

1. Skothein, T.J. (ed.), Handbook of Conducting Polymers, Mercel Dekker, New York, 1986.Google Scholar
2. Miller, R.D. and Michl, J., Chem. Rev. 89, 1359 (1989).Google Scholar
3. Wesson, J.P. and Williams, T.C., J. Polym. Sci., Polym. Chem. Ed. 18, 959 (1980).CrossRefGoogle Scholar
4. West, R., David, L.D., Djurovich, P.I., Stearly, K.L., Srinivasan, K.S.V. and Yu, H., J. Am. Chem. Soc. 103, 7352 (1981).Google Scholar
5. Kepler, R.G., Zeigler, J.M., Harrah, L.A. and Kurtz, S.R., Phys. Rev. 635, 2818 (1987).Google Scholar
6. Kajzar, F., Messier, J. and Rosilio, C., J. Appl. Phys. 60, 3040 (1986).Google Scholar
7. Jeyadev, S., Phillpot, S.R. and Rice, M.J., Mol. Cryst. Liq. Cryst. 169, 433 (1988).Google Scholar
8. Qui, H., Chen, J., Feng, S. and Du, Z., J. Polym. Sci.: Part C: Polym. Lett. 27, 469 (1989).Google Scholar
9. Yi, S.H., Maeda, N., Suzuki, T. and Sato, H., Polym. J. 24, 865 (1992).Google Scholar
10. Harrah, L.A. and Zeigler, J.M., Macromolecules 20, 601 (1987).CrossRefGoogle Scholar