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Optical Absorption, Stability and Structure of NpO2+ Complexes with Dicarboxylic Acids

Published online by Cambridge University Press:  26 February 2011

Guoxin Tian  and
Linfeng Rao
Guoxin Tian
Affiliation:
gtian@lbl.gov, Lawrence Berkeley National Lab, CSD, 70A-1150, 1Cyclotron Rd, Berkeley, CA, 94720, United States, 510 4865141
Linfeng Rao
Affiliation:
LRao@lbl.gov, LBNL, CSD, United States
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Abstract

Complexation of NpO2+ with oxalic acid (OX), 2,2'-oxydiacetic acid (ODA), 2,2'-iminodiacetic acid (IDA) and 2,2'-thiodiacetic acid (TDA), has been studied using spectrophotometry in 1 M NaClO4. Both the position and the intensity of the absorption band of NpO2+ at 980 nm are affected by the formation of NpO2+/dicarboxylate complexes, providing useful information on the complexation strength, the coordination mode and the structure of the complexes.

Keywords

absorptionstructuralcompound
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 893: Symposium JJ – Actinides 2005 – Basic Science, Applications and Technology , 2005 , 0893-JJ05-17
Copyright
Copyright © Materials Research Society 2006

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References

REFERENCES

1. Seaborg, G. T., Loveland, W. D., THE ELEMENTS BEYOND URANIUM (John Wiley & Sons, 1990) pp. 89–94.Google Scholar
2. Choppin, G. R., Nash, K. L., Radiochim. Acta, 1995, 70/71, 225.Google Scholar
3. Sjoblom, R., Hindman, J. C., J. Am. Chem. Soc. 1951, 73, 1744.Google Scholar
4. Gruen, D. M., Katz, J. J., J. Am. Chem. Soc. 1953, 75, 3772.Google Scholar
5. Cooper, J., Reents, W. D., Woods, M., Sjoblom, R., J. C. Sullivan, Inor. Chem. 1977, 16, 1030.Google Scholar
6. Tian, G., Xu, J., Rao, L., Angew. Chem. Int. Ed. 2005, 44, 6200–6203.Google Scholar
7. Stout, B.E., Caceci, M. S., Nectoux, F., Pages, M., Radiochim. Acta, 1989, 46, 181.Google Scholar
8. Jensen, M. P., Nash, K. L., Radiochim. Acta, 2001, 89, 557.Google Scholar
9. Inoue, Y., Tochiyama, O., Polyhedron, 1983, 2 (7), 627–630.Google Scholar
10. Rizkalla, E. N., Nectoux, F., Dabos-Seignon, S., Pages, M., Radiochem. Acta. 1990, 51, 151.Google Scholar
11. Gans, P.; Sabatini, A.; Vacca, A. Version 2.0.Google Scholar
12. (a) Matsika, S., Pitzer, R. M., J. Phys. Chem. A, 2000, 104, 4064;Google Scholar
(b) Matsika, S., Pitzer, R. M., Reed, D. T., J. Phys. Chem. A, 2000, 104, 11983.Google Scholar