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Novel Mocvd Processes for Nanoscale Oxide Thin Films

Published online by Cambridge University Press:  10 February 2011

Tingkai Li
Affiliation:
EMCORE Corporation, 394 Elizabeth Avenue, Somerset, NJ 08873, TingLi@emcore.com
Pete Zawadzkp
Affiliation:
EMCORE Corporation, 394 Elizabeth Avenue, Somerset, NJ 08873, TingLi@emcore.com
Richard A. Stall
Affiliation:
EMCORE Corporation, 394 Elizabeth Avenue, Somerset, NJ 08873, TingLi@emcore.com
Yongfei Zhu
Affiliation:
EMCORE Corporation, 394 Elizabeth Avenue, Somerset, NJ 08873, TingLi@emcore.com Department of Materials Science and Engineering, VPI&SU, Blacksburg, VA 24060
Seshu B. Desu
Affiliation:
EMCORE Corporation, 394 Elizabeth Avenue, Somerset, NJ 08873, TingLi@emcore.com
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Abstract

Nanoscale oxide thin films such as Ba1‐xSrxTiO3 (BST), SrBi2Ta2O9 (SBT), and PbZr1‐xTixO3 (PZT) that have a high dielectric constant and excellent ferroelectric properties have been receiving greatly increased attention, especially for high density memories in next generation integrated circuits. However, with increasing deposition temperature the surface roughness of the films increases, which results in high leakage current, and when the thickness of oxide films is decreased, the apparent bulk‐like properties of thin films tend to worsen due to the increased influence of the interface. To solve these problems, novel MOCVD techniques, plasma enhanced deposition, and a two step process, were developed for high quality oxide thin films.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

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References

1 Chern, C. S., Liang, S., Shi, Z. Q. etc., Appl. Phys. Lett. 64 (23), 3181 (1994).Google Scholar
2 J, Nassef and Milne, Steven J., J. Am. Ceram. Soc. 76 (9) 2321–26 (1993)Google Scholar
3 Hwang, Cheol Seong, Park, Soon Oh, Cho, Hag‐Ju etc. Appl. Phys. Lett. 67 (19) 2819 (1995)Google Scholar
4 Desu, S.B. and Li, T.K., Mat. Sci. and Eng. B 34, L4–L8 (1995).Google Scholar
5 Amanuma, K., Hase, T., and Miyasaka, Y., Appl. Phys. Lett. 66, 221 (1995).Google Scholar
6 Li, T. K., Zhu, Y., Desu, S.B., Peng, C. H. and Nagata, M., Appl. Phys. Lett. 68 (5) 616 (1996)Google Scholar
7 Paz de Araujo, C.A., Cuchiaro, J. D., McMillan, L.D. etc., Nature, 374, 13, 627629 (1995).Google Scholar
8 Tabuchi, M., Kumamoto, T. and Takeda, Y., J. Appl. Phys. 77 (1), 143 (1995).Google Scholar
9 Greenwald, A., Horenstein, M., Ruane, M. etc., Mat. Res. Soc. Symp. Proc. 243, 457 (1992).Google Scholar
10 Tompa, G. S., Nelson, C. R., Saracino, M. A. etc., Appl. Phys. Lett. 55 (1), 62 (1989).Google Scholar
11 Mckee, M. A., Norris, P. E., Stall, R. A. etc., J. Crys. Grow. 107, 445451 (1991).Google Scholar
12 Thompson, A. G., Processing of Advanced Materials, 4, 181188 (1994).Google Scholar
13 Li, T. K., Zawadzki, P. and Stall, R. A., 1996 IEEE/CPMT Int'l Electronics Manufacturing Technology Symposium, 200 (1996).Google Scholar
14 Li, T. K., Zhu, Y., Desu, S.B., Peng, C. H. and Nagata, M., “The Processes, Microstructure and Properties of Ferroelectric SrBi2Ta2O9 Thin films made by Liquid Source Metalorganic Chemical Vapor Deposition,” submitted to Journal of Applied Physics (1996).Google Scholar