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A New Role for Bboron in Advanced Materials

Published online by Cambridge University Press:  15 February 2011

Piotr Kaszynski  and
Dariusz Lipiak
Piotr Kaszynski
Affiliation:
Organic Materials Research Group, Department of Chemistry, Vanderbilt University, Nashville, TN 37235 USA
Dariusz Lipiak
Affiliation:
Organic Materials Research Group, Department of Chemistry, Vanderbilt University, Nashville, TN 37235 USA
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Abstract

Application of highly polar dative bonds of heteroatoms to boron atoms for the preparation of a new class of liquid crystals is discussed. Semiempirical calculations show that compounds incorporating polar bonds of tetra- and higher-coordinated boron centers are characterized by large coaxial dipole moments and relatively large first hyperpolarizabilities β. It is expected that these new liquid crystalline materials will be useful for electrooptical applications.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 374: Symposia ZB – Materials for Optical Limiting , 1994 , 341
Copyright
Copyright © Materials Research Society 1995

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