Hostname: page-component-76fb5796d-zzh7m Total loading time: 0 Render date: 2024-04-26T11:20:11.684Z Has data issue: false hasContentIssue false
  • English
  • Français

Nanoparticulate film precursors to cis solar cells: Spray deposition of Cu-In-Se colloids

Published online by Cambridge University Press:  10 February 2011

D. L. Schulz ,
C. J. Curtis ,
R. A. Flitton  and
D. S. Ginley
D. L. Schulz
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401-3393
C. J. Curtis
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401-3393
R. A. Flitton
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401-3393
D. S. Ginley
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401-3393
Get access

Abstract

The use of nanoparticle colloids for spray deposition of Cu-In-Se precursor films and subsequent thermal treatment to form CuInSe2 (CIS) films has been investigated. In the present study, the metathesis reaction between Na2Se in methanol and metal salts (i.e., Cu(BF4)2 and/or InI3) in pyridine produced CuSe, In2Se3, and CuInSe2.5 nanoparticle colloids. Purified colloid was sprayed onto heated molybdenum-coated sodalime glass substrates to form CuInSe2.5/Mo and In2Se3/CuSe/Mo precursor films. These precursor films were subjected to various thermal treatments in an effort to produce large-grained CIS films from the nano-sized precursors. The annealed CIS films were characterized by scanning electron microscopy (SEM) and x-ray diffraction (XRD). Results of this continuing effort will be discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 501: Symposium FF – Surface Controlled Nanoscale Materials for High-Added… , 1997 , 375
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Tuttle, J.R., Ward, J.S., Duda, A., Berens, T.A., Contreras, M.A., Ramanathan, K.R., Tennant, A.L., Keane, J., Cole, E.D., Emery, K. and Noufi, R., Mat. Res. Soc. Symp. Proc. 426, 143 (1996).Google Scholar
2. Kazmerski, L.L., Renewable and Sustainable Energy Reviews 1, 71 (1997).Google Scholar
3. Schulz, D.L., Curtis, C.J., Flitton, R.A., Wiesner, H., Keane, J., Matson, R.J., Jones, K.M., Parilla, P.A., Noufi, R. and Ginley, D.S., J. Electron. Mater. (in press) (1998).Google Scholar
4. Vervaet, A., Burgelman, M., Clemminck, I. and Casteleyn, M., Proc. 10th European Photovoltaic Solar Energy Conf., (Kluwer, The Netherlands, 1991) pp 900.Google Scholar
5. Garcia, F.J. and Tomar, M.S., Jpn. J. Appl. Phys., Part 1 22, 535 (1983).Google Scholar
6. Probst, V., Karg, F., Rimmasch, J., Riedl, W., Stetter, W., Harms, H. and Eibl, O., Mat. Res. Soc. Symp. Proc. 426, 165 (1996).Google Scholar
7. Joint Commitee for Powder Diffraction Standards, International Center for Diffraction Data, 12 Campus Blvd., Newtown Square, PA 19073, No. 6–680 (Cu2-xSe), No. 20–494 (β-In2Se3), No. 40–1487 (CuInSe2), No. 29–914 (MoSe2).Google Scholar
8. Albin, D.S., Tuttle, J.R. and Noufi, R., J. Electron. Mater. 24, 351 (1995).Google Scholar