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Molecular Self-Assembly Routes to Optically Functional Thin Films: Electroluminescent Multilayer Structures

Published online by Cambridge University Press:  10 February 2011

W. Li ,
J. E. Malinsky ,
H. Chou ,
W. Ma ,
L. Geng ,
T. J. Marks ,
G. E. Jabbour ,
S. E. Shaheen ,
B. Kippelen  and
N. Peyghambarian
...Show all authors
W. Li
Affiliation:
Department of Chemistry and the Materials Research Center, Northwestern University, Evanston, IL 60208-3113, tjmarks@casbah.acns.nwu.edu
J. E. Malinsky
Affiliation:
Department of Chemistry and the Materials Research Center, Northwestern University, Evanston, IL 60208-3113, tjmarks@casbah.acns.nwu.edu
H. Chou
Affiliation:
Department of Chemistry and the Materials Research Center, Northwestern University, Evanston, IL 60208-3113, tjmarks@casbah.acns.nwu.edu
W. Ma
Affiliation:
Department of Chemistry and the Materials Research Center, Northwestern University, Evanston, IL 60208-3113, tjmarks@casbah.acns.nwu.edu
L. Geng
Affiliation:
Department of Chemistry and the Materials Research Center, Northwestern University, Evanston, IL 60208-3113, tjmarks@casbah.acns.nwu.edu
T. J. Marks
Affiliation:
Department of Chemistry and the Materials Research Center, Northwestern University, Evanston, IL 60208-3113, tjmarks@casbah.acns.nwu.edu
G. E. Jabbour
Affiliation:
Optical Science Center, University of Arizona, Tucson, AZ 85721
S. E. Shaheen
Affiliation:
Optical Science Center, University of Arizona, Tucson, AZ 85721
B. Kippelen
Affiliation:
Optical Science Center, University of Arizona, Tucson, AZ 85721
N. Peyghambarian
Affiliation:
Optical Science Center, University of Arizona, Tucson, AZ 85721
J. Andersont
Affiliation:
Department of Chemistry, University of Arizona, Tucson, AZ 85721
P. Lee
Affiliation:
Department of Chemistry, University of Arizona, Tucson, AZ 85721
N. Armstrong
Affiliation:
Department of Chemistry, University of Arizona, Tucson, AZ 85721
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Abstract

This contribution describes the use of layer-by-layer self-limiting siloxane chemisorption processes to self-assemble structurally regular multilayer organic LED (OLED) devices. Topics discussed include: 1) the synthesis of silyl-functionalized precursor molecules for hole transport layer (HTL), emissive layer (EML), and electron transport layer (ETL) self-assembly, 2) the use of layer-by-layer self-assembly for ITO electrode modification/passivation/hole-electron balancing in a vapor-deposited device, 3) the microstructure/chemical characterization of HTL self-assembly using a prototype triarylamine precursor, 4) fabrication and properties of a hybrid self-assembled + vapor deposited two-layer LED, 4) fabrication and properties of a fully self-assembled two-layer OLED.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 488: Symposium J – Electrical, Optical & Magnetic Properties of Organic IV , 1997 , 385
Copyright
Copyright © Materials Research Society 1998

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