Hostname: page-component-77c89778f8-rkxrd Total loading time: 0 Render date: 2024-07-17T15:15:15.122Z Has data issue: false hasContentIssue false

MOCVD of CuInE2 (Where E = S or Se) and Related Materials for Solar Cell Devices

Published online by Cambridge University Press:  10 February 2011

Michael Kemmler
Affiliation:
Department of Chemistry, Imperial College of Science, Technology and Medicine, Exhibition Road, London, SW7 2AZ, UK
Michael Lazell
Affiliation:
Department of Chemistry, and The Manchester Materials Science Centre, Manchester University, Oxford Rd, Manchester, M13 9PLUK
Paul O'brien
Affiliation:
Department of Chemistry, and The Manchester Materials Science Centre, Manchester University, Oxford Rd, Manchester, M13 9PLUK Email addresses: p.obrien@ic.ac.uk
David J. Otwaya
Affiliation:
Department of Chemistry, Imperial College of Science, Technology and Medicine, Exhibition Road, London, SW7 2AZ, UK Email addresses: d.j.otway@ic.ac.uk
Get access

Abstract

Thin film(s) of chalcopyrite CuInE2(where E = S or Se) have been grown by low-pressure metal-organic chemical vapour deposition (LP-MOCVD) using the precursors [In(E2CNMenHexyl)3] and [Cu(E2CNMenHexyl)2]. Similarly, thin films of ME (where M = Zn, Cd; E = S, Se) have been deposited from precursors of general formula [M(E2CNMenHex)2]x. Films were grown on glass between 400 - 500 °C, and characterized by X-ray diffraction, optical spectroscopy (UV/Vis), EDAX and scanning electron microscopy.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 See for example: Nadenau, V., Braunger, D., Hariskos, D., Kaiser, M., Koble, Ch., Ruckh, M., Ruhle, U., Schaffer, R., Schmid, D., Walter, T., Zwergart, S. and Schock, H. W., Prog. Photo. Res. Appl. 3, 363 (1995).Google Scholar
2 Igarashi, O., J. Cryst. Growth 130, 343 (1993).Google Scholar
3 Sagnes, V., Salesse, A., Artaud, M. C., Duchemin, S., Bougnot, J. and Bougnot, G., J. Cryst. Growth 124, 620 (1992).Google Scholar
4 Ouchin, F., Gallon, P., Artaud, M. C., Bougnot, J. and Duchemin, S., Crystal Res. Technol. 31, S513 (1996).Google Scholar
5 Jones, P. A., Jackson, A. D., Lickiss, P. D., Pilkington, R. D. and Tomlinson, R. D., Thin Solid Films 238, 4 (1994).Google Scholar
6 Chichibu, S., Appl. Phys. Lett. 70, 1840 (1997).Google Scholar
7 Hursthouse, M. B., Malik, M. A., Motevalli, M. and O'Brien, P., J. Mat. Chem. 2, 949 (1992).Google Scholar
8 Motevalli, M., O'Brien, P., Walsh, J. R. and Watson, I. M., Polyhedron 15, 2801 (1996).Google Scholar
9 O'Brien, P., Walsh, J. R., Watson, I. M., Hart, L. and Silva, S. R. P., J. Cryst. Growth 167, 133 (1996).Google Scholar
10 Chunggaze, M., McAleese, J., O'Brien, P., Otway, D. J., J. Chem. Soc., Chem. Commun. 833 (1998).Google Scholar
11 O'Brien, P., Otway, D. J. and Walsh, J. R., Adv. Mater., Chem. Vap. Dep. 3, 227 (1997).Google Scholar
12 McAleese, J., O'Brien, P., and Otway, D. J., Adv. Mater., Chem. Vap. Dep. (1997); J. McAleese, P. O'Brien, D. J. Otway, Mat. Res. Soc. Symp. Proc. 485, 157 (1998).Google Scholar
13 Malik, M. A. and O'Brien, P., Adv. Mater. Opt. Elect. 3, 171 (1994).Google Scholar
14 Lazell, M. R., O'Brien, P., Otway, D. J. and Walsh, J. R., Adv. Mater. Opt. Elect accepted for publication (1999).Google Scholar
15 Lazell, M. R., P. O'Brien, Otway, D. J., Park, J.-H., Chem. Mater. accepted for publication (1999).Google Scholar
16 O'Brien, P., Chunggaze, M., Otway, D. J. unpublished results (1999).Google Scholar