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Metalization of Oriented Crystalline Films on Amorphous SiO2/Si

Published online by Cambridge University Press:  25 February 2011

Li Luo
Affiliation:
Center for Materials Science, Los Alamos National Laboratory, Los Alamos, NM 87545
M. Nastasi
Affiliation:
Center for Materials Science, Los Alamos National Laboratory, Los Alamos, NM 87545
C. J. Maggiore
Affiliation:
Center for Materials Science, Los Alamos National Laboratory, Los Alamos, NM 87545
R. F. Pinizzotto
Affiliation:
Center for Materials Characterization, University of North Texas, Denton, TX 76203
H. Yang
Affiliation:
Center for Materials Characterization, University of North Texas, Denton, TX 76203
F. Namavar
Affiliation:
Spire Corporation, Bedford, MA 01730
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Abstract

To meet the needs for vertical integration in microelectronic devices, metalization should not only provide required conducting properties, but should also be suitable for further epitaxial growth so that multilayer structures or heterostructures can be formed. For Si based electronic devices, this has been hindered by the amorphous nature of SiO2. SiO2 layers have been extensively used to passivate the Si surfaces and act as dielectric insulators for forming integrated circuits. In this study, we show that high quality, oriented, metallic nickel disilicide (NiSi2) thin films can be formed on SiO2/Si by combining both ion implantation and e-beam evaporation techniques. The orientation of the Si substrate is maintained in the NiSi2 film as if the SiO2 is not present. RBS/ion channeling and TEM were used to characterize the structures formed and the results indicated that the metallic NiSi2 films were comparable with the films made directly on Si under the same deposition condition. This method should, in general, be applicable to other suicides that have been epitaxially grown on Si.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

1. Murarka, S. P. and Peckerar, M. C., “Electronic Materials, Science and Technology” (Academic Press, NY 1989).Google Scholar
2. Hensel, J. C., Tung, R. T., Poate, J. M., Unterwald, F. C., Appl. Phys. Lett. 44, 913 (1984).CrossRefGoogle Scholar
3. Pinizzotto, R. F., Mat. Res. Soc. Symp. Proc, 27, 265 (1984).CrossRefGoogle Scholar
4. Holland, O. W., Fathy, D., Narayan, J., and Sjoreen, T. P., J. Non-cryst. Solid, 71, 163 (1985).Google Scholar
5. Margail, J., Stoemenos, J., Jaussaud, C. and Bruel, M., Appl. Phys. Lett, 54, 526 (1989).Google Scholar
6. Grunthaner, F. J. and Grunthaner, P. J., Mater. Sci. Rep. 1, 65 (1986).Google Scholar
7. Fenner, D. B., Biegelsen, D. K. and Bringand, R. D., J. Appl. Phys. 66, 419 (1989).Google Scholar
8. Doolittle, L. R., Nucl. Instrum. Methods, B 15, 227 (1986).Google Scholar
9. Tung, R. T., “Silicon Molecular Beam Epitaxy” II, eds. Kasper, K. and Bean, J. C. (CRC Press, Boca Raton FL 1988) 13.Google Scholar
10. Lau, S. S. and Cheung, N. W., Thin Solid Films, 71, 117 (1980).Google Scholar
11. Saitoh, S., Ishiwara, H., Asano, T. and Furukawa, S., Jap. J. Appl. Phys. 20, 1649 (1981).Google Scholar
12. Tung, R. T., Bean, J. C., Gibson, J. M., Poate, J. M., and Jacobson, D. C., Appl. Phys. Lett. 40, 684 (1982).Google Scholar
13. Edington, J. W., “Practical Electron Microscopy in Materials Science” (Reinhold, NY 1976).Google Scholar