Hostname: page-component-8448b6f56d-tj2md Total loading time: 0 Render date: 2024-04-16T14:45:28.351Z Has data issue: false hasContentIssue false
  • English
  • Français

Mechanisms of Silica and Titania Colloidal Particle Formation from Metal Alkoxides

Published online by Cambridge University Press:  28 February 2011

Joseph K. Bailey  and
Martha L. Mecartney
Joseph K. Bailey
Affiliation:
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455
Martha L. Mecartney
Affiliation:
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455
Get access

Abstract

Control of the preparation of monodisperse particles for green body formation can be achieved by understanding the growth mechanism. Growth processes for colloidal silica and titania were followed by cryo-TEM, which allows direct observation of the particles in the liquid state. Structural development was tracked by quenching samples at successive reaction times. The preparation of silica particles involved the formation of ramified species which subsequently collapsed after reaching a certain size. In the titania system, initially small dense nuclei are observed which eventually form uniformly textured homogeneous particles.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 180: Symposium A – Better Ceramics Through Chemistry IV , 1990 , 153
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Stoumlber, W., Fink, A., and Bohn, E., J. Coll. Inf. Sci. 26 62 (1968).Google Scholar
2. Bogush, G.H., Tracy, M.A., and Zukoski, C.F. IV, J. Non-Crystal. Sol. 104 95 (1988).Google Scholar
3. Bogush, G.H. and Zukoski, C.F. IV, in Ultrastructure Processing of Advanced Ceramics, eds. Mackenzie, J.D. and Ulrich, D.R., (John Wiley & Sons, New York, 1989) p. 477.Google Scholar
4. Barringer, B. and Bowen, H.K., J. Amer. Ceram. Soc. 65 C-199 (1982).Google Scholar
5. Diaz-Guemes, M.I., Gonzalez Carreno, T., Serna, C.J., and Palacios, J.M., J. Mater. Sci. Lett. 7, 671 (1988).Google Scholar
6. Bailey, J.K., Bellare, J., and Mecartney, M.L., in Specimen Preparation for Transmission Electron Microscopy of Materials, eds. Bravman, J.C., Anderson, R.M., and McDonald, M.L. (Mat. Res. Soc. Proc. 115, Pittsburgh, 1988) p. 69.Google Scholar
7. Bailey, J.K. and Mecartney, M.L., J. Non-crystal. Sol. 109 198 (1989).Google Scholar
8. Heimenz, P.C., Polymer Chemistry (Marcel Dekker, New York 1984) p. 529.Google Scholar
9. Israelachvili, J.N., Intermolecular and Surface Forces (Academic Press, London, 1985) p. 187.Google Scholar