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Ladder Polymers of High Stability With Macrocyclic Metal Complexes as Subunits

Published online by Cambridge University Press:  10 February 2011

M. Hanack ,
B. Hauschel ,
P. Stihler ,
M. Rack  and
T. Linßen
M. Hanack
Affiliation:
Institut für Organische Chemie, Universität Tübingen, D-72076 Tübingen, Germany
B. Hauschel
Affiliation:
Institut für Organische Chemie, Universität Tübingen, D-72076 Tübingen, Germany
P. Stihler
Affiliation:
Institut für Organische Chemie, Universität Tübingen, D-72076 Tübingen, Germany
M. Rack
Affiliation:
Institut für Organische Chemie, Universität Tübingen, D-72076 Tübingen, Germany
T. Linßen
Affiliation:
Institut für Organische Chemie, Universität Tübingen, D-72076 Tübingen, Germany
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Abstract

Macrocyclic bis-dienes and a diendienophile were prepared in Diels-Alder reactions starting from the bis-dienophilic (hemiporphyrazinato)nickel complex 1. 1 was reacted either with the tetraene 2 or with tetraphenylcyclopentadienone (4). By combination of macrocyclic bisdienes and bis-dienophiles, ladder-type oligomers were synthesized. They are precursors to the corresponding conjugated molecules, which are of interest as potential organic conductors. Monofunctional and bifunctional dienophilic macrocycles were also allowed to react with [60]fullerene to give the corresponding mono- and bis-fullerene adducts.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 413: Symposium W – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials III , 1995 , 465
Copyright
Copyright © Materials Research Society 1996

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References

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