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Irradiation Effects in the Storage and Disposal of Radioactive Ion-Exchange Resins*

Published online by Cambridge University Press:  21 February 2011

Karl J. Swyler ,
Cleveland E. Dodge ,
Ramesh Dayal  and
Allen J. Weiss
Karl J. Swyler
Affiliation:
Brookhaven National Laboratory, Department of Nuclear Energy, Upton, New York
Cleveland E. Dodge
Affiliation:
Brookhaven National Laboratory, Department of Nuclear Energy, Upton, New York
Ramesh Dayal
Affiliation:
Brookhaven National Laboratory, Department of Nuclear Energy, Upton, New York
Allen J. Weiss
Affiliation:
Brookhaven National Laboratory, Department of Nuclear Energy, Upton, New York
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Abstract

Research is under way to characterize the effects of self-irradiation on radwastes which may be generated when organic ion-exchange media are used in water demineralization or decontamination operations at nuclear facilities. External factors affecting the relation between laboratory evaluations and field performance are emphasized. Initial experiments do not yet indicate substantial radiation dose-rate effects on radiolytic gas yields or acid product formation, when (fully swollen) sulfonic acid resins are irradiated in a sealed air environment. At the same time, oxygen gas is removed from the environment of irradiated resins. Interaction between mild steel coupons and acidic species produced in the irradiation induced decomposition of sulfonic acid resin results in irradiation enhanced corrosion. Corrosion rates depend on radiation dose rate, moisture content and resin chemical loading. In some cases, corrosion rates decrease with time, suggesting depletion of acidic species within the resin bed, or a synergistic interaction between resin and corrosion coupon. Implications of these and other results on evaluating field behavior of radwaste containing ion-exchange media are discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 15: Symposium D – Scientific Basis for Nuclear Waste Management VI , 1982 , 455
Copyright
Copyright © Materials Research Society 1983

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Footnotes

*

Work carried out under the auspices of the U.S. Nuclear Regulatory Commission.

References

REFERENCES

1. Gangwer, T., Brookhaven National Laboratory and K.K.S. Pillay, Pennsylvania State University, “Radioactive Loaidng of Ion Exchange Materials: Radiation Releated Areas of Concern,” BNL-NUREG-28647, 1980.CrossRefGoogle Scholar
2. McFarland, R. C., Georgia Institute of Technology, “The Effects of Gamma Radiation on Ion Exchange Resins and Activated Charcoal,” TMI-II-RR-6, 1980. See also R. C. McFarland, “Analysis of Irradiated Ion Exchange Materials, Final Research Report,” Project A60-611, May 1981.Google Scholar
3. Pillay, K.K.S., Pennsylvania State University, “Radiation Effects on Ion Exchangers Used in Radioactive Waste Management,” NE/RWM-80–3, 1980.Google Scholar
4. Barletta, R. E., Swyler, K. J., Chan, S. F., and Davis, R. E., Brookhaven National Laboratory, “Solidification of Epicor-Il Waste Products,” BNL-NUREG-29931R, 1980.Google Scholar
5. Utley, J. W., “The Chemical Effects of Low Energy X-Radiation on Ion- Exchange Resins,” Part I of Ph.D thesis submitted to the faculty of the graduate school of Vanderbilt University, Nashville, TN, June 1959.Google Scholar
6. Kazanjian, A. R. and Horrell, D. R., “Radiation Effects on Ion-Exchange Resins-I. Gamma Irradiation of Dowex 50 XW,” USAEC Report RFP-2140, Rocky Flats Division, Golden, CO, 1974.CrossRefGoogle Scholar
7. Egorov, E. V. and Novikov, P. D., “Action of Ionizing Radiation on Ion- Exchange Materials,” Atomizdat, Moscow, 1965, Israel Program for Scientific Translations, Jerusalem, 1967.Google Scholar
8. Gillen, K. T. and Clough, R. L., “Occurrence and Implications of Radiation Dose Rate Effects for Material Aging Studies,” Rad. Phys. Chem. 10, 679–687, (1981).Google Scholar
8a Clough, R. L. and Gillen, K. T., Radiation-Thermal Degradation of PE and PVC: Mechanism of Synergism and Dose Rate Effects,– Rad. Phys. Chem. 18, 661–669 (1981).Google Scholar
9. MacKenzie, D. R., Lin, M., and Barletta, R. E., Brookhaven National Laboratory, Permissible Radionuclide Loading for Organic Ion Exchange Resins From Nuclear Power Plants,– BNL-NUREG-30668, January 1982.CrossRefGoogle Scholar
10. Gangwer, T. E. and Pillay, K. K. S., “Radiation-Induced Corrosion of Mild Steel in Contact With Ion-Exchange Materials,” Nuclear Technology 58, 548 (1982).CrossRefGoogle Scholar