Hostname: page-component-848d4c4894-cjp7w Total loading time: 0 Render date: 2024-06-19T13:40:32.286Z Has data issue: false hasContentIssue false
  • English
  • Français

Ionic Conduction in Nanoscale Films of Yttrium-Doped Barium Zirconate

Published online by Cambridge University Press:  26 February 2011

Joon Hyung Shim ,
Turgut M Gur  and
Fritz B Prinz
Joon Hyung Shim
Affiliation:
shimm@stanford.edu, Stanford University, Mechanical Engineering, 440 Escondido Mall, Bldg 530-226, Stanford, CA, 94305, United States, 650-387-8019, 650-723-5034
Turgut M Gur
Affiliation:
turgut@stanford.edu, Stanford University, Material Science Engineering, Stanford, CA, 94305, United States
Fritz B Prinz
Affiliation:
fbp@cdr.stanford.edu, Stanford University, Mechanical Engineering, Stanford, CA, 94305, United States
Get access

Abstract

Proton conductivity of yttrium-doped barium zirconate grown on MgO(100) using pulsed laser deposition (PLD) has been explored as a function of film thickness (60∼670nm) related to crystal and grain structure in the nano scale. Highly textured thin film (60nm) without significant grain separation showed high ionic conductivity close to the bulk BYZ value while thick polycrystalline samples showed lower values with clear grain and grain boundary formation.

Keywords

ionic conductorthin filmlaser ablation
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 972: Symposium AA – Solid-State Ionics—2006 , 2006 , 0972-AA01-07
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Iwahara, H., Uchida, H., Ono, K., and Ogaki, K., J. Electrochem. Soc. 135, 2 (1988).Google Scholar
2. Slade, R. C. T., and Singh, N., Solid State Ionics, Diffusion & Reactions 46, 1/2 (1991).Google Scholar
3. Munch, W., Seifert, G., Kreuer, K. D., and Maier, J., Solid State Ionics 97, 1–4 (1997).Google Scholar
4. Kreuer, K. D., Annual Review of Materials Research 33, (2003).Google Scholar
5. Kuwata, N., Sata, N., Tsurui, T., and Yugami, H., Japanese Journal of Applied Physics, Part 1 (Regular Papers, Short Notes & Review Papers) 44, 12 (2005).Google Scholar
6. Iwahara, H., Yajima, T., Hibino, T., Ozaki, K., and Suzuki, H., Solid State Ionics 61, 1–3 (1993).Google Scholar
7. Babilo, P., and Haile, S. M., J Am Ceram Soc 88, 9 (2005).Google Scholar
8. Haile, S. M., Staneff, G., and Ryu, K. H., J. Mater. Sci. 36, 5 (2001).Google Scholar
9. Kreuer, K. D., Schonherr, E., and Maier, J., Solid State Ionics 70–71, pt 1 (1994).Google Scholar
10. Kreuer, K. D., Solid State Ionics, Diffusion & Reactions 125, 1/4 (1999).Google Scholar
11. Bohn, H. G., and Schober, T., J Am Ceram Soc 83, 4 (2000).Google Scholar