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Introduction of Organic Moieties into Transition-Metal Oxide Matrices via Phosphonate Groups

Published online by Cambridge University Press:  10 February 2011

P.H. Mutin ,
C. Delenne ,
D. Medoukali ,
R. Corriu  and
A. Vioux
P.H. Mutin
Affiliation:
UMR 5637, Université de Montpellier 2, cc007, 34095 Montpellier Cedex 5
C. Delenne
Affiliation:
UMR 5637, Université de Montpellier 2, cc007, 34095 Montpellier Cedex 5
D. Medoukali
Affiliation:
UMR 5637, Université de Montpellier 2, cc007, 34095 Montpellier Cedex 5
R. Corriu
Affiliation:
UMR 5637, Université de Montpellier 2, cc007, 34095 Montpellier Cedex 5
A. Vioux
Affiliation:
UMR 5637, Université de Montpellier 2, cc007, 34095 Montpellier Cedex 5
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Abstract

Transition metal oxide / phenylphosphonate hybrids with M/P ratios ranging from 1 to 5, (M= Ti, Zr) and metal phosphonates (M/P = 0.5) have been prepared by a sol-gel process involving in a first step the non-hydrolytic condensation between metal alkoxide and phosphonic acid leading to M-O-P bonds, followed by the hydrolysis-condensation of the remaining M-OR groups. The composition, texture and structure of the materials were investigated using EDX, TGA, XRD, IR and 31P NMR.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 519: Symposium O – Organic/Inorganic Hybrid Materials , 1998 , 345
Copyright
Copyright © Materials Research Society 1998

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