Hostname: page-component-77c89778f8-rkxrd Total loading time: 0 Render date: 2024-07-20T23:27:17.940Z Has data issue: false hasContentIssue false

Influence of chemical bath deposition parameters on the formation of CuInS2 / Zn(Se,O) junctions for thin film solar cells

Published online by Cambridge University Press:  21 March 2011

A.M. Chaparro
Affiliation:
Dep.Energías Renovables. CIEMAT. Avda. Complutense, 22 28040-Madrid (Spain)
M.T. Gutiérrez
Affiliation:
Dep.Energías Renovables. CIEMAT. Avda. Complutense, 22 28040-Madrid (Spain)
J. Herrero
Affiliation:
Dep.Energías Renovables. CIEMAT. Avda. Complutense, 22 28040-Madrid (Spain)
J. Klaer
Affiliation:
Hahn-Meitner-Institut (SE3). Glienicker Str. 100, 14109 Berlin (Germany)
Get access

Abstract

Thin film solar cells of CuInS2/Zn(Se,O)/ZnO configuration have been studied as a function of the Zn(Se,O) buffer layer deposition parameters. Deposition of the buffer films was carried out by the chemical bath deposition (CBD) method, at different bath temperatures and compositions, and followed in situ with a quartz crystal microbalance. The CBD conditions were chosen to grow Zn(Se,O) buffer layers under different kinetic regimes but maintaining the same buffer thickness. The cells have been characterised with current-voltage and quantum efficiency measurements. Light soaking effects and medium term stability have been checked. It is found that Zn(Se,O) grown under predominant electroless kinetics gives rise to buffer films richer in oxygen, which allow for higher fill factors, higher efficiencies (around 10%) and stability of the cells. These cells show however lower open circuit potential. On the other hand, Zn(Se,O) buffers grown under chemical regime become richer in selenium, which gives rise to cells with higher open circuit potential, but lower fill factor, conversion efficiency and stability. Light soaking effects are also more important with the chemically grown buffers.

Type
Research Article
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Fahrenbruch, A.L. and Bube, R., Fundamentals of solar cells, (Academic Press, 1983).Google Scholar
2. Guillemoles, J.F., Kronik, L., Cahen, D., Jasenek, A. and Schock, H.W., J.Phys.Chem. 104, 48494862 (2000).Google Scholar
3. Chaparro, A.M., Maffiotte, C., Herrero, J. and Gutiérrez, M.T., Surf. and Int.Anal. 30, 522526 (2000).Google Scholar
4. Chaparro, A.M., Gutiérrez, M.T. and Herrero, J., sent to J.Electrochem.Soc. Google Scholar
5. Klaer, J., Bruns, J., Henninger, R., Siemer, K., Klenk, R., Ellmer, K. and Bräunig, D., Semic.Sci.Technol. 13, 14561458 (1998).Google Scholar
6. Kanazawa, K.K., in New characterisation techniques for thin-film polymers, Tong, H.-M. and Nguyen, L.T., Editors, p.125 (John Wiley & Sons, Inc., N. York, 1990).Google Scholar
7. Chaparro, A.M., Maffiotte, C., Gutiérrez, M.T., Herrero, J., Klaer, J., Siemer, K., Bräunig, D., Thin Solid Films 387/1-2, 104107 (2001).Google Scholar