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In Situ X-Ray Investigation of Novel Protonic Conductors

Published online by Cambridge University Press:  25 February 2011

Veniamin Sh. Shekhtman
Affiliation:
Institute of Solid State Physics, Chernogolovka, Russia
Ruben A. Dilanyan
Affiliation:
Institute of Solid State Physics, Chernogolovka, Russia
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Abstract

Systematic X-ray diffraction studies of thermal expansion in CsHSO4, CsDSO4, RbHSO4 and Rb3H(SeO4)2 crystals have been carried out. An analysis of the results showed that the fast protonic conductivity is closely connected with the characteristic features of the structure, symmetry and orientation of hydrogens bonds in the crystals of MeXAO4 (Me=NI4, Rb, Cs; X= D,H; A= S,Se) family.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

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