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In Situ X-RAY Diffraction Studies of Li+ Insertion into V6O13

Published online by Cambridge University Press:  25 February 2011

C. Lampe-Önnerud ,
T. Gustafsson  and
J.O. Thomas
C. Lampe-Önnerud
Affiliation:
Institute of Chemistry, Uppsala University, Box 531, S–751 21 Uppsala, Sweden.
T. Gustafsson
Affiliation:
Institute of Chemistry, Uppsala University, Box 531, S–751 21 Uppsala, Sweden.
J.O. Thomas
Affiliation:
Institute of Chemistry, Uppsala University, Box 531, S–751 21 Uppsala, Sweden.
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Abstract

A fast in situ X-ray powder diffraction set-up working in transmission mode is used to explore the structural changes occurring on Li+ insertion into the active V6O13 component of the cathode in a thin-film < Li I polymer electrolyte | V6O13 > battery. It is confirmed that the V6O13 is indeed converted reversibly into three discrete phases, LixV6O13 for x = 1, 4 and 8, as the fully charged cell (ca. 3.OV) is discharged to 1.8V. The effect on the insertion process of repeated cycling with different currents has been studied. Cell collapse was induced after ca. 35 cycles for 0.2 mA/cm2. This was not reflected, however, in any significant change in the diffraction pattern from the battery. Moreover, the battery returned to normal functioning after lying on open circuit for 7 days. A gradual loss of reflection intensity is observed, but no particle line-broadening. The implications of these results are discussed as they relate to the nature of the solid-state insertion process of Li+ into V6O13.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 293: Symposium U – Solid State Ionics III , 1992 , 49
Copyright
Copyright © Materials Research Society 1993

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References

[1] West, K., Zachau-Christiansen, B. and Jacobsen, T., Electrochim. Acta, 28, 1829, (1983).Google Scholar
[2] Steele, B. C. H., Lagos, G. E., Spurdens, P. C., Forsyth, C. and Foord, A. D., Solid State Ionics, 9–10, 391, (1983).Google Scholar
[3] Murphy, D. W., Christian, P. A., DiSalvo, F. J. and Carides, J. N., J. Electrochem. Soc. 126, 497, (1979).Google Scholar
[4] Chaklanabish, N.C. and Maita, H. S., J. Thermal Anal. 31, 1243, (1986).Google Scholar
[5] Chaklanabish, N. C. and Maiti, H. S., Solid State Ionics, 21, 207, (1986).Google Scholar
[6] Zachau-Christiansen, B., PhD thesis, Fysisk-Kemisk Institut, Technical University of Denmark, DK-2800, Lyngby, Denmark, 1985.Google Scholar
[7] Theobald, F., Cabala, R. and Bernard, J., J.Solid State Chem. 17, 431, (1976).Google Scholar
[8] Zachau-Christiansen, B., West, K. and Jacobsen, T., Mat. Res. Bull. 20, 485(1985).Google Scholar
[9] Yde-Andersen, S.. Private communication.Google Scholar
[10] West, K., Zachau-Christiansen, B., Jacobsen, T. and Atlung, S., J. Power Sources, 14, 235 (1985).Google Scholar
[11] Murphy, D.W., Christian, P.A., DiSalvo, F.J., Carides, J.N. and Waszczak, J.V., J. Electrochem. Soc. 128,2053 (1981).Google Scholar
[12] Abraham, K.M., Goldman, J.L. and Dempsey, M.D., J.Electrochem. Soc. 128, 2493, (1981).Google Scholar
[13] West, K., Zachau-Christiansen, B., Oestergard, M. J. L. & Jacobsen, T., J. Power Sources, 20 165 (1987).Google Scholar
[14] Colbow, K.M., Dahn, J.R. and Haering, R.R., J. Power Sources, 26, 301 (1989).Google Scholar
[15] Dahn, J.R., Py, M.A. and Haering, R.R., Can. J. Phys. 60, 307, (1982).Google Scholar
[16] Dahn, J.R. and McKinnon, W.R., Solid State Ionics, 23, 1, (1987).Google Scholar
[17] US Patent 4,748,542Google Scholar
[18] US Patent 4,830,939Google Scholar
[19] Lundsgaard, J. S., Yde-Andersen, S., Koksbang, R., Shackle, D. R., Austin, R. A. and Fauteux, D., 2nd ISPE, Siena, Italy, 14-16 June 1989, pp. 395.Google Scholar
[20] Koksbang, R., Olsen, I.I., Toender, P.E., Knudsen, N., Lundsgaard, J.S. and de-Andersen, S.Y, J. Power Sources, 32, 175, (1990).Google Scholar
[21] Yde-Andersen, S., Koksbang, R., Flemming, F., Olsen, I.I., Toender, P.E., Petersen, K.P, Consigny, M. and Broendum, K., Electrochem. Soc. Fall Meeting, Seattle. 14-19 Oct. 1990, Ext. Abstr. No. 30.Google Scholar
[22] Koksbang, R., Flemming, F., Olsen, I. I., Toender, P. E., Petersen, K. P., Consigny, M., Broendum, K. and Yde-Andersen, S., Electrochem. Soc. Fall Meeting, Seattle, 14-19 Oct. 1990, Ext. Abstr. No. 25.Google Scholar
[23] Huq, R., Koksbang, R., Toender, P. E. and Farrington, G. C., Proc. of 2nd Asian Conf.on Solid State Ionics, Beijing, 29 Oct. - 1 Nov. 1990.Google Scholar
[24] Huq, R., Farrington, G. C., Koksbang, R. and Toender, P. E., Electrochem. Soc., Fall Meeting, Seattle, 14-19 Oct. 1990, Ext. Abstr. No. 24.Google Scholar
[25] Gustafsson, T., Thomas, J.O., Koksbang, R. and Farrington, G.C., Electrochim. Acta. 37, 1639, (1992).Google Scholar