Hostname: page-component-7c8c6479df-995ml Total loading time: 0 Render date: 2024-03-28T19:37:19.438Z Has data issue: false hasContentIssue false

Group 12 Thiolates: Syntheses, Characterization and Decomposition Pathways

Published online by Cambridge University Press:  22 February 2011

Gertrud KrÄuter
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, FL 32306-3006
Virgil L. Goedken
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, FL 32306-3006
Bernhard NeumÜller
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, FL 32306-3006
W. S. Rees Jr.
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, FL 32306-3006
Get access

Abstract

Zinc- and cadmium bis(alkylthiolate) compounds have been prepared and converted into the appropriate binary metal sulfides by thermal treatment. Several mercury chlorothiolates have been synthesized and characterized by single crystal X-ray diffraction. Their decomposition pathways are discussed. The prepared binary metal sulfides have been studied by XRPD and - in selected cases - by particle size determination. The volatile co-products have been isolated and characterized by GC/MS.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Cowley, A. H. and Jones, R. A., Angew. Chem. Int. Engl. Ed. 28, 1208 (1989).Google Scholar
2. Hursthouse, M. B., Malik, M. A., Motevalli, M., O'Brian, P., Organometallics 10, 730 (1991).Google Scholar
3. Bochmann, M., Webb, K. J., Harman, M., Hursthouse, M. B., Angew. Chem. Int. Engl. Ed. 29, 100 (1990).Google Scholar
4. Bochmann, M., Webb, K. J., Hursthouse, M. B., Mazid, M., J. Chem. Soc., Dalton Trans. 1991, 2317.Google Scholar
5. Brennan, J. G., Siegrist, T., Carrol, P. J., Stuczynski, S. M., Brus, L. E., Steigerwald, M. L., J. Am. Chem. Soc. 111, 4141 (1989).Google Scholar
6. Osakada, K., Yamamoto, T., J. Chem. Soc. Chem. Commun. 1987, 1117; Inorg. Chem. 30, 2328 (1991).Google Scholar
7. Dance, I. G., Polyhedron 5, 1037 (1986).Google Scholar
8. Biscanini, P., Foresti, E., Pradella, G., J. Chem. Soc., Dalton Trans. 1984, 953.Google Scholar
9. Rees, W. S. Jr., KrAuter, G., Goedken, V. L., MRS Symposiums Proceedings 283, (Materials Research Society, Pittsburgh, PA, 1993), pp. 859864.Google Scholar
10. Rees, W. S. Jr., and Krauter, G., Abstract N6.1 presented at the 1993 MRS Fall Meeting, Boston, MA, 1993.Google Scholar
11. Rees, W. S. Jr., and Krauter, G., Recent Advances in the Chemistry of Main Group Elements, Symposiums Proceedings (Gordon and Breach, Langhorne, PA, 1994), accepted for publication.Google Scholar