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Fabrication and Modification of Metal Nanocluster Composites Using Ion and Laser Beams

Published online by Cambridge University Press:  21 February 2011

R.F. Haglund Jr. ,
D.H. Osborne Jr. ,
R.H. Magruder III ,
C.W. White ,
R.A. Zuhr ,
P.D. Townsend ,
D.E. Hole  and
R.E. Leuchtner
R.F. Haglund Jr.
Affiliation:
Department of Physics and Astronomy and
D.H. Osborne Jr.
Affiliation:
Department of Physics and Astronomy and
R.H. Magruder III
Affiliation:
Department of Applied and Engineering Science, Vanderbilt University, Nashville, TN 37235.
C.W. White
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831
R.A. Zuhr
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831
P.D. Townsend
Affiliation:
School of Mathematical and Physical Sciences, University of Sussex, Brighton BN1 9QH, UK
D.E. Hole
Affiliation:
School of Mathematical and Physical Sciences, University of Sussex, Brighton BN1 9QH, UK
R.E. Leuchtner
Affiliation:
and Department of Physics and Astronomy, University of New Hampshire, Durham, NH 03824–3568
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Abstract

Metal nanocluster composites have attractive properties for applications in nonlinear optics. However, traditional fabrication techniques — using melt-glass substrates — are severely constrained by equilibrium thermodynamics and kinetics. This paper describes the fabrication of metal nanoclusters in both crystalline and glassy hosts by ion implantation and pulsed laser deposition. The size and size distribution of the metal nanoclusters can be modified by controlling substrate temperature during implantation, by subsequent thermal annealing, or by laser irradiation. We have characterized the optical response of the composites by absorption and third-order nonlinear-optical spectroscopies; electron and scanning-probe microscopies have been used to benchmark the physical characteristics of the composites. The outlook for controlling the structure and nonlinear optical response properties of these nanophase materials appears increasingly promising.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 354: Symposium A – Beam Solid Interactions for Materials Synthesis and Characterization , 1994 , 629
Copyright
Copyright © Materials Research Society 1995

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References

1 Bloemer, M.J., Haus, J.W. and Ashley, P.R., J. Opt. Sex:. Am. B 7, 790 (1990).Google Scholar
2 Hache, F., Ricard, D., Flytzanis, C. and Kreibig, U., Appl. Phys. A 47, 347 (1988).Google Scholar
3 Haus, J.W., Kalyaniwalla, N., Inguva, R., Bloemer, M. and Bowden, C.M., J. Opt. Soc. Am. B 6, 797 (1989).Google Scholar
4 Flytzanis, C., Hache, F., Klein, M.C., Ricard, D. and Roussignol, Ph., Prog. Opt. 29, Wolf, E. ed. , North Holland, Amsterdam (1991).Google Scholar
5 Magruder, R.H. III, Haglund, R.F. Jr. , Yang, Li, White, C.W., Yang, Lina, Dorsinville, R. and Alfano, R.R., Appl. Phys. Lett. 62, 1730 (1993).Google Scholar
6 Arnold, G.W. and Borders, J.A., J. Appl. Phys. 48, 1488 (1977)Google Scholar
7 Haglund, R.F. Jr. , Yang, L., Magruder, R.H. III, Wittig, J.E., Becker, K. and Zuhr, R.A., Opt. Lett. 18, 373 (1993).Google Scholar
8 See, for example,Gavrin, A. and Chien, C.L., J. Appl. Phys. 67, 938 (1990).Google Scholar
9 Bamford, C.R., Colour Generation and Control in Glass, Glass Science and Technology, Vol. II (Amsterdam: Elsevier, 1977).Google Scholar
10 Magruder, R.H. III, Haglund, R.F. Jr. , Yang, Li and Zuhr, R.A., J. Appl. Phys. 76, 781 (1994)Google Scholar
11 Yang, Li, Osborne, D.H., Haglund, R.F. Jr. , Magruder, R.H., White, C.W., Zuhr, R.A. and Hosono, H., Appl. Phys. A, to be published.Google Scholar
12 Neeves, A.E. and Birnboim, M.H., J. Opt. Soc. Am. B 6, 787 (1989).Google Scholar
13 Yang, Li, Becker, K., Smith, F.M., Magruder, R.H. III, Haglund, R.F. Jr. , Yang, Lina, Dorsinville, R., Alfano, R.R. and Zuhr, R.A., J. Opt. Soc. Am. B 11, 457 (1994).Google Scholar
14 Jain, R. and Lind, R.C., J. Opt. Soc. Am. 73, 647 (1983).Google Scholar
15 Leuchtner, R.E. and Haglund, R.F. Jr. , MRS Fall Meeting 1994, Paper Za7. 4.Google Scholar
16 Cheung, J. and Sankur, H., CRC Crit. Rev. Solid State Mater. Sei. 15, 63 (1988). See also K. Saenger, Chap 20, in Pulsed Laser Deposition, D.B. Chrisey and G. Hubler, eds. (New York: John Wiley and Sons, 1994).Google Scholar
17 Pond, J.M., Carroll, K.R., Horwitz, J.S., Chrisey, D.B., Osofsky, M.S., and Cestone, V.C., Appl. Phys. Lett. 59, 3033 (1991).Google Scholar
18 Jo, W., Yi, G-C., Noh, T.W., Ko, D-K, Cho, Y.S., and Kwun, S-I., Appl. Phys. Lett. 61, 1516 (1992). Y. Shibata, K. Kaya, K. Akashi, Appl. Phys. Lett. 61, 1000–2 (1992).Google Scholar
19 Sayer, M., Kumar, C.V.R.V., Barrow, D., Zou, L. and Amm, D.T., in Ferroelectric Thin Films II, eds.Kingon, A.I., Myers, E.R. and Tuttle, B., Mater. Res. Soc. Symp. Proc. 243, 39 (1992.Google Scholar
20 Polla, D.L., Robbins, W.P., Tamagawa, T. and Ye, C., in Smart Materials Fabrication and Materials for Micro-Electro-Mechanical Systems, eds.Jardine, A.P., Johnson, G.C., Crowson, A. and Allen, M., Mater. Res. Soc. Symp. Proc. 276, 3 (1992).Google Scholar
21 Cotell, C.M., Chrisey, D.B., Grabowski, K.S., Sprague, J.A., and Gossett, C.R., J. Appl. Biomaterials 3, 87 (1992). CM. Cotell, Appl. Surf. Sei. , in press.Google Scholar
22 Leuchtner, R.E., Chrisey, D.B., Horwitz, J.S., and Grabowski, K.S., Surface and Coatings Tech. 51, 476 (1992).Google Scholar
23 Magruder, R.H. III, Haglund, R.F. Jr. , Yang, Li, Wittig, J.E. and Zuhr, R.A., J. Appl. Phys. 76, 708 (1994).Google Scholar
24 Magruder, R.H. III, Kinser, D.L., Wittig, J.E. and Zuhr, R.A., Properties and Characteristics of Optical Glass III, Proc. SPIE 1761, 180 (1992).Google Scholar
25 Wood, R.A., Townsend, P.D., Skelland, N.D., Hole, D.E., Barton, J. and Alfonso, C.N., J. Appl. Phys. 74, 5754 (1993).Google Scholar
26 Sheik-Bahae, M., Said, A.A., Wei, T., Hagan, D.J. and VanStryland, E.W., IEEE J. Quant. Elect. 26, 760 (1990).Google Scholar
27 Becker, K., Yang, L. and Haglund, R.F. Jr. , to be submitted to J. Opt. Soc. Am. B, 1995.Google Scholar
28 Shimizu, T., Itoh, N. and Matsunami, N., J. Appl. Phys. 64, 3663 (1988). A. Miotello and R. Kelly, Nucl. Instrum. Meth. Phys. Res. B 65, 217 (1992). S.Y. Park, Ph.D. Thesis, Vanderbilt University, unpublished (1994).Google Scholar
29 Hoheisel, W., Jungmann, K., Vollmer, M., Weidenauer, R. and Träger, F., Phys. Rev. Lett. , 60, 1649 (1988). M. Vollmer, R. Weidenauer, W. Hoheisel, U. Schulte and F. Träger, Phys. Rev. B 40, 12 509 (1990).Google Scholar