Hostname: page-component-77c89778f8-9q27g Total loading time: 0 Render date: 2024-07-16T20:59:53.190Z Has data issue: false hasContentIssue false
  • English
  • Français

Epitaxial Growth of Sr0.3Ba0.7Nb2O6 Thin Films Prepared by Sol-Gel Process

Published online by Cambridge University Press:  10 February 2011

Keishi Nishio ,
Jirawat Thongrueng ,
Yuichi Watanabe  and
Toshio Tsuchiya
Keishi Nishio
Affiliation:
Dep. of Materials Sci. and Tech. Science University of Tokyo, Noda Chiba, 278-8510, JAPAN
Jirawat Thongrueng
Affiliation:
Dep. of Materials Sci. and Tech. Science University of Tokyo, Noda Chiba, 278-8510, JAPAN
Yuichi Watanabe
Affiliation:
Dep. of Materials Sci. and Tech. Science University of Tokyo, Noda Chiba, 278-8510, JAPAN
Toshio Tsuchiya
Affiliation:
Dep. of Materials Sci. and Tech. Science University of Tokyo, Noda Chiba, 278-8510, JAPAN
Get access

Abstract

Abstruct

We succeeded in the preparation of strontium-barium niobate (Sr0.3Ba0.7Nb2O6 : SBN30)that have a tetragonal tungsten bronze type structure thin films on SrTiO3 (100), STO, or La doped SrTiO3 (100), LSTO, single crystal substrates by a spin coating process. LSTO substrate can be used for electrode. A homogeneous coating solution was prepared with Sr and Ba acetates and Nb(OEt)5 as raw materials, and acetic acid and diethylene glycol monomethyl ether as solvents. The coating thin films were sintered at temperature from 700 to 1000°C for 10 min in air. It was confirmed that the thin films on STO substrate sintered above 700°C were in the epitaxial growth because the 16 diffraction spots were observed on the pole figure using (121) reflection. The <130> and <310> direction of the thin film on STO were oriented with the c-axis in parallel to the substrate surface. However, the diffraction spots of thin film on LSTO substrate sintered at 700°C were corresponds to the expected pattern for (110).

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 606: Symposium NN – Chemical Processing of Dielectrics, Insulators & Electronic Ceramics , 1999 , 181
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Jamieson, P. B., Abrahams, S. C. and Bernstein, J. L., J. Chem. Phys.,48 [11], 5048–57 (1968).Google Scholar
2 Trubelja, M. P., Ryba, E. and Smith, D. K., J. Mater. Sci., 31, 1435–43 (1996).Google Scholar
3 Neurgaonkar, R. R., Hall, W. F., Oliver, J. R., Ho, W. W. and Cory, W. K., Ferroelectrics, 87, 167–79 (1988).Google Scholar
4 Glass, A. M., J. Appl. Phys., 40, 4699–713 (1969); 41,2268(E) (1970).Google Scholar
5 Nishiwaki, S., Takahashi, J. and Kodaira, K., J. Ceram. Soc. Jpn., 103 [12], 1246–50 (1995).Google Scholar
6 Lenzo, P. V., Spencer, E. G. and Ballman, A. A., Appl. Phys. Lett., 11 [1], 23–24 (1967).Google Scholar
7 Xu, R., Xu, Y., Chen, C. J. and Mackenzie, J. D., J. Mater. Res., 5 [5], 916–18 (1990).Google Scholar
8 Sakamoto, W., Yogo, T., Kikuta, K., Ogiso, K., Kawase, A. and Hirano, S., J. Am. Ceram. Soc., 79 [9], 2283–88 (1996).Google Scholar
9 Neurgaonka, R. R., Kalisher, M. H., Cim, T. C., Staples, E. J. and Keester, K. L., Mater. Res. Bull., 15, 1235–40 (1980).Google Scholar
10 Thaxter, J. B., Appl. Phys. Lett., 15 [7], 210–12 (1969)Google Scholar
11 Sakka, S., Science of Sol-Gel method, in Japanese, Agne Shoufu-sha (1988).Google Scholar
12 Yanagida, H. and Nagai, M., Science of Ceramics, in Japanese, Gihoudou Shyuppan (1993).Google Scholar
13 Hirano, S., Yogo, T., Kikuta, K.,Urahata, H., Isobe, Y., Morishita, T., Ogiso, K. and Ito, Y., Mat. Res. Soc. Symp. Proc., Vol. 271, 331–38 (1992)Google Scholar
14 Kuo, Yu-Fu and Tseng, Tseung-Yuen, J. Mat. Sci., 31, 6361–68 (1996)Google Scholar
15 Hu, YI, J. Mat. Sci., 31, 4255–59 (1996)Google Scholar
16 Nishio, Keishi, Seki, Nobuhiro, Thongrueng, Jirawat, Watanabe, Yuichi and Tsuchiya, Toshio, J. Sol-Gel Sci. and Tech., 16, 37–45 (1999)Google Scholar
17 Nakano, T., Kumagai, M. and Funahashi, T., Proceedings of Fall Meeting The Ceramic Society of Japan, 242–243 (1990)Google Scholar