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Electronic Properties of some Ternary and Quaternary Oxides of the VIII B and I B Transition Elements: Application to High Tc Superconductivity

Published online by Cambridge University Press:  21 February 2011

M. Pouchard ,
J-C. Grenier ,
J-P. Doumerc ,
G. Demazeau ,
J-P. Chaminade ,
A. Wattiaux ,
P. Dordor  and
P. Hagenmuller
M. Pouchard
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
J-C. Grenier
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
J-P. Doumerc
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
G. Demazeau
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
J-P. Chaminade
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
A. Wattiaux
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
P. Dordor
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
P. Hagenmuller
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
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Abstract

In the scope of the Goodenough model, a brief review of the electronic properties of some 3d transition elements (M = Fe, Co, Ni and Cu ) is given; the main relevant electronic and structural parameters are emphasized. Then a special attention is focussed on N/(N−1) and N/(N−2) electron mixed valence compounds.

Finally some particular features of copper are discussed and their relevance to high Tc superconductors is pointed out:

-the srong covalency of Cu-O bondings involving a possible delocalization of the hole between trivalent copper and oxygen,

-the existence of low and high spin electronic configurations for CuIII,

-the disproportionation of Cu2+ and its role in the formation of hole pairs,

Cu-O distances very close for the three successive oxidation states of copper favouring the disproportionation process.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 156: Symposium M – High Temperature Superconductors: Relationships Between Properties, Structure, and Solid State Chemistry , 1989 , 13
Copyright
Copyright © Materials Research Society 1989

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References

REFERENCES

1- Goodenough, J.B., ”Metallic Oxides”, Prog. Solid State Chem., 5, 145 (1971)Google Scholar
2- Buffat, B., Demazeau, G., Pouchard, M. and Hagenmuller, P., Proc. Indian Acad. Sci., 93, 313 (1984)Google Scholar
3- Goodenough, J.B. and Raccah, P.M., J. Appl.Phys., 36, 1031 (1965)Google Scholar
4- Bhide, V.G., Rajoria, D.S., Rama-Rao, G. and Rao, C.N.R., Phys. Rev., B 6, 1021 (1972)Google Scholar
5- Wold, A., Post, B. and Banks, E. J. Amer.Chem. Soc.,79, 4911 (1957)Google Scholar
6- Demazeau, G., Pouchard, M. and Hagenmuller, P., J. Sol. State Chem., 18, 159 (1976)Google Scholar
7- Demazeau, G., Marty, J-L., Buffat, B., Dance, J.M., Pouchard, M., Dordor, P. and Chevalier, B. Mat Res.Bull., 17, 37 (1982)Google Scholar
8- Rao, C.N.R., Ganguly, P., Singh, K.K. and Ram, R.A. Mohan, J. Sol. State Chem., 72, 14 (1988)Google Scholar
9- Goodenough, J.B., Mott, N.F., Pouchard, M., Demazeau, G. and Hagenmuller, P. Mat. Res. Bull., 8, 647 (1973)Google Scholar
10- Demazeau, G., Marboeuf, A., Pouchard, M. and Hagenmuller, P., J. Sol. State Chem., 3, 582 (1971)Google Scholar
11- Goodenough, J.B. and Ramasesha, S., Mat. Res. Bull., 17, 383 (1982)Google Scholar
12- Buttrey, D.J., Ganguly, P., Honig, J.M., Rao, C.N.R., Schartman, R.R. and Subbanna, G.N., J. Sol. State Chem., 74, 233 (1988)Google Scholar
13- Grenier, J-C., Pouchard, M. and Hagenmuller, P., Structure and Bonding, (Springer Verlag, Berlin ) 47, 1 (1981)Google Scholar
14- Day, P. and Robin, R., Adv. Inorg. Chem., 10, 247 (1966)Google Scholar
15- Grenier, J-C., Ea, N., Pouchard, M. and Sekkina, A., Mat. Res. Bull., 19, 1301 (1984)Google Scholar
16- Oda, H., Yamaguchi, Y., Takei, H. and Watanabe, H., J. Phys. Soc. Japan, 42(1), 101 (1977)Google Scholar
17- Bonnet, J-P., Grenier, J-C., Onillon, M., Pouchard, M. and Hagenmuller, P. Mat. Res. Bull., 14, 67 (1979)Google Scholar
18- Grenier, J-C., Pouchard, M., Hagenmuller, P., Henche, M.J.R., Vallet, M., Calbet, J.M.G. and Alario-Franco, M.A. Rev. Chim. min.,20, 726 (1983)Google Scholar
19- Doumerc, J-P., Vlasse, M., Pouchard, M. and Hagenmuller, P., J. Solid State Chem., 14, 144 (1975)Google Scholar
20- Takano, M., Nakanishi, N., Takeda, Y., Naka, S. and Takada, T., Mat. Res. Bull., 12, 923 (1977)Google Scholar
21- Gleitzer, C. and Goodenough, J.B., Structure and Bonding (Springer Verlag Berlin) 61, 1 (1985)Google Scholar
22- Prassides, K. and Day, P., Inorg. Chem., 24, 545 (1985)Google Scholar
23- Pouchard, M., Grenier, J.C. and Doumerc, J.P., C.R. Acad. Sc. Paris, 305, 571 (1987)Google Scholar
24- Demazeau, G., Parent, C., Pouchard, M. and Hagenmuller, P., Mat. Res. Bull., 79 913 (1972)Google Scholar
25- Klemm, W., Wehrmeyer, G. and Bade, H. Z. Elektrochem. Ber. Bunsenges. Physik Chem. 63, 56 (1959)Google Scholar
26- Goodenough, J.B., Demazeau, G., Pouchard, M. and Hagenmuller, P., J. Sol. State Chem., 8, 325 (1973)Google Scholar
27- Goodenough, J.B., Mat. Res. Bull. 23, 401 (1988)Google Scholar
28- Chakraverty, B.K., Sarma, D.D. and Rao, C.N.R. Physica C, 156, 413 (1988)Google Scholar
29- Simon, A., Angew. Chem.,99, 602 (1987)Google Scholar
30- Sleight, A.W. Chemtronics, 2, 116 (1987)Google Scholar
31- Chestnut, D.B., J. Chem. Phys., 40, 405 (1964)Google Scholar
32- Slichter, C.P. and Drickamer, H.G., J. Chem. Phys., 56, 2142 (1972)Google Scholar
33- Varma, C.M., Schmitt-Rink, S. and Abrahams, E., Sol. State Com., 62(10), 681 (1987)Google Scholar