Hostname: page-component-8448b6f56d-sxzjt Total loading time: 0 Render date: 2024-04-20T00:46:36.262Z Has data issue: false hasContentIssue false
  • English
  • Français

Electronic Properties of Poly(Para-Phenylenes) Under High Pressure

Published online by Cambridge University Press:  10 February 2011

W. Graupner ,
S. Guha ,
S. Yang ,
M. Chandrasekhar ,
H. R. Chandrasekhar ,
G. Leising ,
U. Scherf  and
K. Müllen
W. Graupner
Affiliation:
Institut für Festkörperphysik, Technische Universität Graz, A-8010 Graz, Austria.
S. Guha
Affiliation:
Department of Physics & Astronomy, University of Missouri, MO 65211 Columbia , USA
S. Yang
Affiliation:
Department of Physics & Astronomy, University of Missouri, MO 65211 Columbia , USA
M. Chandrasekhar
Affiliation:
Department of Physics & Astronomy, University of Missouri, MO 65211 Columbia , USA
H. R. Chandrasekhar
Affiliation:
Department of Physics & Astronomy, University of Missouri, MO 65211 Columbia , USA
G. Leising
Affiliation:
Institut für Festkörperphysik, Technische Universität Graz, A-8010 Graz, Austria.
U. Scherf
Affiliation:
Max-Planck-Institut für Polymerforschung, D-55128 Mainz, Germany.
K. Müllen
Affiliation:
Max-Planck-Institut für Polymerforschung, D-55128 Mainz, Germany.
Get access

Abstract

We have studied the photoluminescence emission spectra of polycrystalline and amorphous powder samples of phenylene-type polymers and oligomers. In order to modulate both intrachain and interchain interactions these investigations were performed at hydrostatic pressures up to 70 kbar and in a tOmperature range of 20 to 300 K. We report characteristic changes of the emission spectrum which depend on both the molecular environment as well as the intramolecular bond configuration.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 488: Symposium J – Electrical, Optical & Magnetic Properties of Organic IV , 1997 , 873
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Chiang, C. K., Fincher, C. R., Park, Y. W., Heeger, A. J., Shirakawa, H., Louis, E. J., Gau, S. C., MacDiarmid, A. G., Phys. Rev. Lett. 39, 1098 (1977).Google Scholar
[2] Primary Photoexcitations in Conjugated Polymers: Molecular Exciton versus Semiconductor Band Model, ed. by Sariciftci, N. S., World Scientific, Singapore 1996.Google Scholar
[3] Cornil, J., Heeger, A. J., Bredas, J. L., Chem. Phys. Lett. 272, 463 (1997).Google Scholar
[4] refs. [4]-[10] in [3]; List, E. J. W., Graupner, W., Wohlgenannt, M., Leising, G., Partee, J., Shinar, J., Schlichting, P., Rohr, U., Geerts, Y., Scherf, U., Müllen, K., Optical Materials in print; J. Partee, J. Shinar, W. Graupner, G. Leising, S. W. Jessen, A. J. Epstein, Y. Ding, T. J. Barton, SPIE Proceedings 3145 in print.;Google Scholar
[5] Tasch, S., Niko, A., Leising, G., Scherf, U., Appi. Phys. Lett. 68, 1090 (1996).Google Scholar
[6] Tasch, S., Brandstätter, C., Meghdadi, F., Leising, G., Athouel, L., Froyer, G., Adv. Mat. 9, 33 (1997).Google Scholar
[7] Resel, R., Meghdadi, F., Koch, N., Leising, G., Thin Solid Films in print.Google Scholar
[8] Socci, E. P., Farmer, B. L., Adams, W. W., J. Polym. Sci. Polym. Phys. Ed. 31, 1975 (1993).Google Scholar
[9] Graupner, W., Leising, G., Lanzani, G., Nisoli, M., de Silvestri, S., Scherf, U., Phys. Rev. Lett. 76, 847 (1996).Google Scholar
[10] Piaggi, A., Lanzani, G., Bongiovanni, G., Mura, A., Graupner, W., Meghdadi, F., Leising, G., Phys. Rev. B 56, 10133 (1997).Google Scholar
[11] Zenz, C., Graupner, W., Tasch, S., Leising, G., Müllen, K., Scherf, U., Appl. Phys. Lett. 71, 2566 (1997).Google Scholar
[12] Kranzelbinder, G., Byrne, H. J., Hallstein, S., Roth, S., Leising, G., Scherf, U., Phys. Rev. B 56,1632 (1997).Google Scholar
[13] Graupner, W., Eder, S., Tasch, S., Leising, G., Lanzani, G., Nisoli, M., De Silvestri, S., Scherf, U., Journal of Fluorescence 7, 195s (1997).Google Scholar
[14] Graupner, W., Partee, J., Shinar, J., Leising, G., Scherf, U., Phys. Rev. Lett. 77, 2033 (1996).Google Scholar
[15] Jayaraman, A., Rev. Mod. Phys. 55, 65 (1983); A. Jayaraman, Rev. Sci. Instrum. 57, 1013 (1986).Google Scholar
[16] Dunstan, D. J., Rev. Sci. Instrum. 60, 3789 (1989).Google Scholar
[17] Webster, S., Batchelder, D. N., Polymer 37, 4961 (1996).Google Scholar
[18] Graupner, W., Eder, S., Petritsch, K., Leising, G., Scherf, U., Synthetic Metals 84, 507 (1997).Google Scholar
[19] Yoshino, K., Nakao, K., Onoda, M., Sugimoto, R., J. Phys. Cond. Matt. 1, 1009 (1989).Google Scholar
[20] Rossi, L., Graupner, W., Resel, R., Meghdadi, F., Leising, G., Sannicolo, F., Tubino, R., Materials Research Society Meeting, Boston, Dec 1–5, 1997 Google Scholar
[21] Hanfland, M., Brillante, A., Syassen, K., Stamm, M., Fink, J., J. Chem. Phys. 90, 1930 (1989)Google Scholar
[22] Hess, B. C., Kanner, G. S., Vardeny, Z., Phys. Rev. B 47, 1407 (1993).Google Scholar
[23] Moses, D., Feldblum, A., Ehrenfreund, E., Heeger, A. J., Chung, T. C., MacDiarmid, A. G., Phys. Rev. B 26, 3361 (1982).Google Scholar
[24] Lacey, R. J., Batchelder, D. N., Pitt, G. D., J. Phys. C: Solid State Phys. 17, 4529 (1984).Google Scholar
[25] Rice, S. A., Jortner, J. in Physics of Solids at High Pressure ed. by Tomizuka, C. ., Emrick, R. M., Academic Press, London 1965.Google Scholar
[26] Webster, S., Batchelder, D. N., Macromol. Symp. 87, 177 (1994).Google Scholar
[27] Lochner, K., Bässler, H., Sowa, H., Ahgbahs, H., Chem. Phys. 52, 179 (1980).Google Scholar