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Effect of Ag and Au doping on the photocatalytic activity of TiO2 supported on textile fibres

Published online by Cambridge University Press:  01 February 2011

Mohammed Jasim Uddin
Affiliation:
mohammed.uddin@unito.it, University of Turin, Department of Chemistry IFM, Via P. Giuria 7, Turin, 10125, Italy, +39 011 670 7859, +39 011 670 7855
Federico Cesano
Affiliation:
federico.cesano@unito.it, University of Turin, Department of Chemistry IFM and Nanostructured Interfaces and Surfaces (NIS), Centre of Excellence, Via P. Giuria 7, Turin, 10125, Italy
Domenica Scarano
Affiliation:
domenica.scarano@unito.it, University of Turin, Department of Chemistry IFM and Nanostructured Interfaces and Surfaces (NIS), Centre of Excellence, Via P. Giuria 7, Turin, 10125, Italy
Silvia Bordiga
Affiliation:
silvia.bordiga@unito.it, University of Turin, Department of Chemistry IFM and Nanostructured Interfaces and Surfaces (NIS), Centre of Excellence, Via P. Giuria 7, Turin, 10125, Italy
Adriano Zecchina
Affiliation:
adriano.zecchina@unito.it, University of Turin, Department of Chemistry IFM and Nanostructured Interfaces and Surfaces (NIS), Centre of Excellence, Via P. Giuria 7, Turin, 10125, Italy
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Abstract

A simple method to develop TiO2, Ag or Au-doped TiO2 thin films on cotton textiles for advanced applications, is reported. The homogeneous TiO2 thin films have been deposited on cotton textiles by using sol-gel method at low temperature (100° C), whereas Ag and Au nanoparticles were then deposited on the pre-existent TiO2 films by photoreduction. The Ag/TiO2 covered cotton fibres show multichromic behaviour (grey colour under visible light and brown colour upon ultraviolet light exposure) as well as photoactivity. The Au-TiO2 film coated the cotton textile produces a purple colour with excellent self cleaning properties. The original and treated fibres have been characterized by several techniques (SEM, HRTEM, FTIR, Raman, UV–vis spectroscopy and XRD).

Type
Research Article
Copyright
Copyright © Materials Research Society 2008

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References

1. Fujishima, A. and Honda, K., Nature, 1972, 238, 3738.Google Scholar
2. Usseglio, S., Damin, A., Scarano, D., Bordiga, S., Zecchina, A. and Lamberti, C., J. Am. Chem. Soc., 2007, 129, 28222828.Google Scholar
3. Anpo, M. and Takeuchi, M., J. Catal., 2003, 216, 505516.Google Scholar
4. Carp, O., Huisman, C. L. and Reller, A., Prog. Solid State Chem., 2004, 32, 33177.Google Scholar
5. Choi, W. Y., Termin, A. and Hoffmann, M. R., J. Phys. Chem., 1994, 98, 1366913679.Google Scholar
6. Wu, C.-G., Chao, C.-C. and Kuo, F.-T., Catal. Today, 2004, 97, 103112.Google Scholar
7. Rodrigues, S., Ranjit, K. T., Uma, S., Martyanov, I. N. and Klabunde, K. J., J. Adv. Mater., 2005, 17, 24672471.Google Scholar
8. Kapoor, P. N., Uma, S., Rodriguez, S. and Klabunde, K. J., J. Mol. Catal., A, 2005, 229, 145150.Google Scholar
9. Brook, L. A., Evans, P., Foster, H. A., Pemble, M. E., Steele, A., Sheel, D. W. and Yates, H. M., Photochem, J.. Photobiol. A-Chem., 2007, 187, 5363.Google Scholar
10. Ohko, Y., Tatsuma, T., Fujii, T., Naoi, K., Niwa, C., Kubota, Y. and Fujishima, A., Nat. Mater., 2003, 2, 2931.Google Scholar
11. Mele, G., Ciccarella, G., Vasapollo, G., Garcia-Lopez, E., Palmisano, L. and Schiavello, M., Appl. Catal. B-Environ., 2002, 38, 309319.Google Scholar
12. Corma, A., Serna, P. and Garcia, H., J. Am. Chem. Soc., 2007, 129, 63586359.Google Scholar
13. Uddin, M. J., Cesano, F., Bonino, F., Bordiga, S., Spoto, G., Scarano, D. and Zecchina, A., J. Photochem. Photobiol. A-Chem., 2007, 189, 286294.Google Scholar
14. Uddin, M. J., Cesano, F., Scarano, D., Bonino, F., Agostini, G., Spoto, G., Bordiga, S. and Zecchina, A., Photochem, J.. Photobiol. A-Chem., 2008 (in press).Google Scholar
15. Uddin, M. J., Cesano, F., Bertarione, S., Bonino, F., Bordiga, S., Scarano, D. and Zecchina, A., J. Photochem. Photobiol. A-Chem., 2008, 196, 165173.Google Scholar
16. Moharram, M. A., Nasr, T. Z. A. E. and Hakeem, N. A., J of Pol Sc.: Pol Lett Ed, 1981, 19, 183187.Google Scholar
17. Birks, L. S. and Friedman, H., J. App. Phy, 1946, 17, 687692.Google Scholar
18. Kato, S., Hirano, Y., Iwata, M., Sano, T., Takeuchi, K. and Matsuzawa, S., Appl. Catal. BEnviron., 2005, 57, 109115.Google Scholar
19. Matsubara, K. and Tatsuma, T., Adv. Mater., 2007, 19, 2802±.Google Scholar
20. Corma, A. and Serna, P., Science, 2006, 313, 332334.Google Scholar