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Dynamics of Flexible Polyions in Solution: Ionic Strength Effects

Published online by Cambridge University Press:  21 February 2011

Hedi Mattoussi ,
Kenneth H. Langley  and
Frank E. Karasz
Hedi Mattoussi
Affiliation:
Polymer Science & Engineering Department, University of Massachusetts
Kenneth H. Langley
Affiliation:
Department of Physics and Astronomy, University of Massachusetts, Amherst, MA 01003.
Frank E. Karasz
Affiliation:
Polymer Science & Engineering Department, University of Massachusetts
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Abstract

Measurements of the collective diffusion coefficient, for polyelectrolyte solutions at high ionic strength and in the dilute regime, are reported. The data are discussed within the framework of a persistent chain with electrostatic contribution to account for the Coulomb interactions.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 177: Symposium V – Macromolecular Liquids , 1989 , 71
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

[1] Morawetz, M., Macromolecules in Solutions, V. XXI, in High Polymers, Wiley, New York (1975).Google Scholar
[2] Nagasawa, M., Takahaski, A. in Light Scattering from Polymer Solutions, Ed. by Huglin, M. B., Wiley, New York (1972) Ch. 16.Google Scholar
[3] Lin, S. G., Lee, W. L., Schurr, J. M., Biopolymers, 17, 1041 (1978).Google Scholar
[4] Schurr, J. M., Chem. Phys. 45, 113 (1980).Google Scholar
[5] Odjik, T., Howart, A. C., J. Poly. Sci., Poly. Phy. Ed., 16, 627 (1978).Google Scholar
[6] Berry, G. C., Proceedings MRS, Boston Meeting, November (1988).Google Scholar
[7] Mattoussi, H., Karasz, F.E., Langley, K. H., to be published.Google Scholar
[8] Berne, B., Pecora, R., Dynamic Light Scattering, Wiley, New York (1976).Google Scholar
[9] Koene, R. S., Mandel, M., Macromolecules, 21, 3015 (1983).Google Scholar
[10] Machado, J., Denton, F. R. III, Shlenoff, J. B., Karasz, F. R., Lahti, P. M., J. Polym. Sci., Part B Polym. Phys., Ed., 27, 199 (1989).Google Scholar
[11] Yamakawa, H., Fujii, M., Macromolecules, 6, 407 (1973).Google Scholar
[12] Yamakawa, H., Modern Theory of Polymer Solutions, Harper and Row, New York (1971).Google Scholar
[13] Mattoussi, H., o'Donohue, S., Karasz, F. E., in preparation.Google Scholar
[14] Casassa, E. F., Berry, G. C., in Comprehensive Polymer Science, Vol.2, Cha. 2, Ed. by Allen, S. & al, Pergamon Press, Oxford (1989).Google Scholar
[15] Berry, G. C., in Encyclopedia of Polymer Science & Engineering, (Mark, H. et al Ed.), Wiley, New York ( 1987) p. 721.Google Scholar