Hostname: page-component-76fb5796d-x4r87 Total loading time: 0 Render date: 2024-04-26T10:57:04.085Z Has data issue: false hasContentIssue false
  • English
  • Français

Development and Characterization of Novel Complex Hydrides Synthesized via Molten State Processing

Published online by Cambridge University Press:  01 February 2011

Ragaiy Zidan ,
Kirk L Shanahan ,
Donald L. Anton ,
Arthur R Jurgensen  and
Jennifer Pittman
Ragaiy Zidan
Affiliation:
ragaiy.zidan@srnl.doe.gov, Savannah River National Laboratory, Energy Security, 773-41A/ 247, Savannah River Site, Aiken, SC, 29808, United States, (803)725-1726, (803)725-4129
Kirk L Shanahan
Affiliation:
kirk. shanahan@srnl.doe.gov, Savannah River National Laboratory, United States
Donald L. Anton
Affiliation:
Donald.Anton@srnl.doe.gov, Savannah River National Laboratory, United States
Arthur R Jurgensen
Affiliation:
arthur.jurgensen@srnl.doe.gov, Savannah River National Laboratory, United States
Jennifer Pittman
Affiliation:
jennifer.pittman@srs.gov, Savannah River National Laboratory, United States
Get access

Abstract

This study is aimed at developing novel hydrides for hydrogen storage through a new synthesis technique utilizing high hydrogen overpressure at elevated temperatures denoted as Molten State Processing, MSP. This synthesis technique holds the potential of fusing different known complex hydrides at elevated temperatures and pressures to form new complexes having different sorption and thermodynamic properties. Complex hydrides produced by this method (e.g. NaMgH3, K3AlH6 and Na2LiAlH6) were identified through structural determination and thermodynamic characterization.

Keywords

chemical substitutionalloyhydrogenation
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 885: Symposium A – The Hydrogen Cycle – Generation, Storage and Fuel Cells , 2005 , 0885-A07-02
Copyright
Copyright © Materials Research Society 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1- Sandrock, G., in Yurum, Y. (ed.), Hydrogen Energy Systems: Production and Utilization of Hydrogen and Future Aspects, NATO ASI Series, Kluwer Academic Publishers, 1994 p 253 Google Scholar
2- Sandrock, Gary, Journal of Alloys and Compounds 293–295 (1999) 877 Google Scholar
3- Bogdanovic, B. and Schwickardi, M., J. Alloys and Compounds, 1–9 (1997) 253 Google Scholar
4- Bogdanovic, B., and Schwickardi, M., Patent application PCT WO 97/03919Google Scholar
5- Zidan, R., Takara, S., Hee, A., and Jensen, C. M., Journal of Alloys and Compounds, 285 (1999) 119 Google Scholar
6- Bogdanovic, B., Brand, R. A., Marjanovic, A., Schwickardi, M. and Tolle, Joachim, Journal of Alloys and Compounds 302 (2000) 36–58 Google Scholar
7- Huot, J., Boily, S., Guther, V., Schulz, R., Journal of Alloys and Compounds 383 (1999) 304 Google Scholar
8- Zaluski, L., Zaluska, A., Strom-Olsen, J.O., Journal of Alloys and Compounds 290 (1999) 71 Google Scholar
9- Zaluska, A., Zaluski, L., Strom-Olsen, J.O., Journal of Alloys and Compounds 307 (2000) 157 Google Scholar
10- Zidan, R., “Complex hydrides for Hydrogen Storage” Patent Application No 03778089.71218Google Scholar
11- Brinks, H.W., Hauback, B.C., Jensen, C.M. and Zidan, R. “Synthesis and crystal structure of Na2LiAlD6 ” Journal of Alloys and Compounds 392 (2005) 27 Google Scholar