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Design and Syntheses of Poly(Norbornenyldecaborane) Precursors to Boron Carbide and Boron-Carbide/Silicon-Carbide Ceramics

Published online by Cambridge University Press:  01 February 2011

Xiaolan Wei ,
Daniel T. Welna ,
Jared D. Bender ,
Larry G. Sneddon  and
Harry R. Allcock
Xiaolan Wei
Affiliation:
Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104
Daniel T. Welna
Affiliation:
Department of Chemistry, The Pennsylvania State University, University Park, PA 16802
Jared D. Bender
Affiliation:
Department of Chemistry, The Pennsylvania State University, University Park, PA 16802
Larry G. Sneddon
Affiliation:
Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104
Harry R. Allcock
Affiliation:
Department of Chemistry, The Pennsylvania State University, University Park, PA 16802
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Abstract

Poly(norbornenyldecaborane) (PND) was synthesized via ruthenium catalyzed ring opening metathesis polymerization and was found to be a good single-source polymeric boron carbide precursor. Polymer blends of PND and allylhydridopolycarbosilane (AHPCS) were also found to be excellent precursors to boron-carbide/silicon-carbide composite materials.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 848: Symposium FF – Solid-State Chemistry of Inorganic Materials V , 2004 , FF1.8
Copyright
Copyright © Materials Research Society 2005

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