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Defects and Phonon Assisted Optical Transitions in Si Nanocrystals

Published online by Cambridge University Press:  09 August 2011

G Allan ,
C Delerue  and
M Lannoo
G Allan
Affiliation:
Institut d'Electronique et de Microélectronique du Nord, Département Institut Supérieur d'Electronique du Nord, BP 69, 59652 Villeneuve d'Ascq Cedex, FRANCE, delerue@isen.fr
C Delerue
Affiliation:
Institut d'Electronique et de Microélectronique du Nord, Département Institut Supérieur d'Electronique du Nord, BP 69, 59652 Villeneuve d'Ascq Cedex, FRANCE, delerue@isen.fr
M Lannoo
Affiliation:
Institut d'Electronique et de Microélectronique du Nord, Département Institut Supérieur d'Electronique du Nord, BP 69, 59652 Villeneuve d'Ascq Cedex, FRANCE, delerue@isen.fr
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Abstract

Phonon-assisted and zero-phonon radiative transitions in nanoscale silicon quantum dots are studied using a new approach which combines a full calculation of the confined electronic eigenstates and vibration modes. We predict that the confinement, combined with the indirect bandgap of bulk silicon, must have several important consequences on the luminescence of a single silicon dot: i) a large broadening of the peaks, in the range of 10s of meV for a 3 nm dot, in spite of the atomic-like electronic structure of the dot ii) a great sensitivity of the spectrum to the size and the shape of the dot. We obtain that phonon-assisted transitions always dominate, even for size below 2 nm. Finally, we show that the radiative recombination in presence of an oxygen related surface defect (Si=O) is also assisted by optical phonons.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 536: Symposium F – Microcrystalline & Nanocrystalline Semiconductors - 1998 , 1998 , 39
Copyright
Copyright © Materials Research Society 1999

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