Hostname: page-component-848d4c4894-ttngx Total loading time: 0 Render date: 2024-05-18T05:52:39.527Z Has data issue: false hasContentIssue false

The Coupling of Chemical and Transport Processes in Near-Field Modelling

Published online by Cambridge University Press:  28 February 2011

S.M. Sharland
Affiliation:
Theoretical Physics Division, Harwell Laboratory, Didcot, Oxon OXll ORAU.K
P.W. Tasker
Affiliation:
Theoretical Physics Division, Harwell Laboratory, Didcot, Oxon OXll ORAU.K
C.J. Tweed
Affiliation:
Theoretical Physics Division, Harwell Laboratory, Didcot, Oxon OXll ORAU.K
Get access

Abstract

Near-field modelling is concerned with the description of the migration, chemical and degradation processes that may occur within an engineered radioactive waste repository and its immediate environs. The object is to gain understanding of such processes in order to predict the long-time evolution of the repository and to assess the degree of containment provided by the proposed engineered construction. The conditions of primary interest to our programme concern the waste contained within a steel canister and buried in a concrete environment within a clay geology. The chemistry of the near-field is controlled in that it is the consequence of the choice of near-field components, but it may be extremely complex. Intrusion of external groundwater and degradation of the chosen materials will lead to variations in the chemistry in both space and time. It is vitally important to understand these changing chemical conditions since they determine the solubility and sorption of any released radionuclides. In this paper, we describe the computer program CHEQMATE (CHemical EQuilibrium with Migration And Transport Equations), which has many applications in modelling various changes in chemistry in the near-field. The program combines an ionic migration code with the geochemical program PHREEQE [1]. The program maintains local chemical equilibrium in the system as the transport processes evolve. The program includes automatic mineral accounting; solid phases are added or removed from the equilibrium as precipitation or dissolution occurs. We illustrate the use of the CHEQMATE program with an example of a coupled chemical and transport problem, particularly relevant to the near-field of a waste repository.

Type
Research Article
Copyright
Copyright © Materials Research Society 1987

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

l.Parkhurst, D.L., Thorstenson, D.C. and Plummer, L.N., U.S.Geological Survey, Water-Resources Investigations, 8096 (1985)Google Scholar
2. Harker, A.H., Sharland, S.M. and Tasker, P.W., ‘A Mathematical Model of Uniform Corrosion of Intermediate Level Waste Canisters in Concrete’, AERE Report TP.1115 (1985)Google Scholar
3. Sharland, S.M. and Tasker, P.W., ‘The Aeration Period of a Model Nuclear Waste Repository’, AERE Report TP.1182 (1986)Google Scholar
4. Sharland, S.M., Tasker, P.W. and Tweed, C.J., ‘The Evolution of the Oxidation Potential in the Pore Water of a Model Nuclear Waste Repository’, report in preparation.Google Scholar
5. Atkinson, A. and Hearne, J.A., AERE Report AERE-R 11465 (1984)Google Scholar
6. Flynn, C.M., Chem. Rev. 84 3141 (1984)Google Scholar