Hostname: page-component-77c89778f8-n9wrp Total loading time: 0 Render date: 2024-07-17T17:17:40.383Z Has data issue: false hasContentIssue false

Corrosion Behavior of Zirconium Alloy Nuclear Fuel Cladding

Published online by Cambridge University Press:  21 February 2011

Anna C. Fraker
Affiliation:
Metallurgy Division, National Institute of Standards and Technology, Gaithersburg, MD 20899
Jonice S. Harris
Affiliation:
Metallurgy Division, National Institute of Standards and Technology, Gaithersburg, MD 20899
Get access

Abstract

Zircaloy−2 and −4 are used as nuclear fuel cladding. Both alloys are more than ninety-eight percent zirconium and are corrosion resistant to various media. Electrochemical measurements using polarization techniques have been made on these alloys in aqueous media with a pH of 8.5 and varying ionic concentration (1X and 10X) at temperatures of 22°C and 95°C. Results showed that under the test conditions of the study these alloys passivated and had negligible corrosion rates, but there were some variations in passivation due to surface preparation and some crevice corrosion was observed. Data are presented and discussed in terms of passivity, breakdown potential and susceptibility to localized corrosion.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Title 10 Code of Federal Regulations (CFR) Part 60-Disposal of High-Level Radioactive Wastes in Geologic Repositories: Section 60.113(a)(ii)(B), United States Nuclear Regulatory Commission, (1988).Google Scholar
2. Fraker, Anna C., Corrosion Behavior of Zircaloy Spent Fuel Cladding in a Repository, Nat. Inst. Stds. Tech. (NISTIR)-89-4114, July, (1989).Google Scholar
3. Soo, P., Ed., Review of Waste Package Verification Tests, NUREG/CR- 3091, BNL-NUREG-51630, Vol. 6, July, (1985), pp. 138139.Google Scholar
4. ASTM F 746-87, Standard Test Method for Pitting and Crevice Corrosion Standards, of Metallic Surgical Implant Materials, Annual Book of ASTM Medical Devices, Vol. 13, Am. Soc. for Testing and Mater., Philadelphia, PA 19103, (1988), pp. 221226.Google Scholar
5. Cheng, B. and Adamson, R. B., Mechanistic Studies of Zircaloy Nodular Corrosion, Presented at Am. Soc. for Test. and Mater. 7th Internl. Conf. on Zirconium in the Nuclear Industry, Strasbourg, France, June 2427, (1985).Google Scholar