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Constrainment Effects of Interleaved Organic Molecules into Layered Double Hydroxides

Published online by Cambridge University Press:  01 February 2011

Marc Dubois ,
El Mostafa Moujahid ,
Jean-Pierre Besse  and
Fabrice Leroux
Marc Dubois
Affiliation:
Laboratoire des Matériaux Inorganiques, CNRS-UMR n°6002, Université Blaise Pascal, 63177 Aubière cédex, France; E-mail: fleroux@chimtp-univ.bpclermont.fr
El Mostafa Moujahid
Affiliation:
Laboratoire des Matériaux Inorganiques, CNRS-UMR n°6002, Université Blaise Pascal, 63177 Aubière cédex, France; E-mail: fleroux@chimtp-univ.bpclermont.fr
Jean-Pierre Besse
Affiliation:
Laboratoire des Matériaux Inorganiques, CNRS-UMR n°6002, Université Blaise Pascal, 63177 Aubière cédex, France; E-mail: fleroux@chimtp-univ.bpclermont.fr
Fabrice Leroux
Affiliation:
Laboratoire des Matériaux Inorganiques, CNRS-UMR n°6002, Université Blaise Pascal, 63177 Aubière cédex, France; E-mail: fleroux@chimtp-univ.bpclermont.fr
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Abstract

Incorporation and subsequent stabilization of organic molecules into layered double hydroxide are investigated. Through two types of hybrid materials, organic dyes and aniline-based monomers interleaved between LDH materials of cation composition Zn2Al and Cu2Cr respectively, it is shown that the effect of the constrainment is revealed by the interactions different according to the molecule size and stacking as exemplified by dye molecules, orange 6 and green 25 acids and two aniline-based monomers, m-amino-4-benzenesulfonic and 3-aniline-1-propanesulfonic acids.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 847: Symposium EE – Organic/Inorganic Hybrid Materials , 2004 , EE9.19
Copyright
Copyright © Materials Research Society 2005

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