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Conductivity in Poly(Ethylene Oxide) Complexed with Mixed Alkali Metal Salts

Published online by Cambridge University Press:  16 February 2011

Byoung-Koo Choi  and
Young–Wa Kim
Byoung-Koo Choi
Affiliation:
Department of science education, Dankook University, Yongsan, Seoul 140–714, Korea
Young–Wa Kim
Affiliation:
Department of science education, Dankook University, Yongsan, Seoul 140–714, Korea
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Abstract

Conductivity has been measured for mixed alkali systems of LixNa1-xClO4 (PEO)n with n = 6, 16 and 40, and a mixed anion system of LiClxI1−x(PEO)16 complexes with varying concentrations of x. In the LixNa1−xClO4 (PEO)n complexes, it shows no unusual conductivity behavior. In the LiClxI1−x(PEO)16 complexes, the conductivity shows positive deviation from additivity in the mixed-anion region and the mixed-anion effect is also observed in the semicrystalline-toamorphous transition temperature.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 369: Symposium U – Solid State Ionics IV , 1994 , 535
Copyright
Copyright © Materials Research Society 1995

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References

1. Isard, J.O., J. Non-Cryst. Solids, 1, 235 (1969).Google Scholar
2. Day, D.E., J. Non-Cryst. Solids, 21, 343 (1976).Google Scholar
3. Sato, H., Solid State Ionics, 40/41, 725 (1990).Google Scholar
4. Carette, B., Ribes, M. and Souquet, J.L., Solid State Ionics 9/10, 735 (1983).Google Scholar
5. Minami, T., J. Non-Cryst. Solids, 73, 273 (1985).Google Scholar
6. Moryoussef, A., Bonnat, M., Fouletier, M. and Hicter, P., in Proc. 6th RISO Int. Symp. Metallurgy and Materials Science, edited by Poulsen, F.W., Andersen, N.H., Clausen, K., Skaarup, S. and Sorensen, O.T. (Roskilde, The Hague 1985), p. 335.Google Scholar
7. Dupon, R., Papke, B.L., Ratner, M.A., Whitmore, D.A. and Shriver, D.F., J. Am. Chem. Soc. 104, 6247 (1982).Google Scholar
8. Kelly, I.E., Owen, J.R. and Steele, B.C.H., J. Power Sources, 14, 13 (1985).Google Scholar
9. MacCallum, J.R., Tomlin, A.S., Tunstall, D.P. and Vincent, C.A., Br. Polym. J. 20, 203 (1988).Google Scholar
10. Tunstall, D.P., Tomlin, A.S., Gray, F.M., MacCallum, J.R. and Vincent, C.A., J. Phys. Condens. Matter, 1, 4035 (1989).Google Scholar
11. Yang, H. and Farrington, G.C., J. Polym. Sci. B, 31, 157 (1993).Google Scholar
12. Robitaille, C.D. and Fauteux, D., J. Electrochem. Soc. 133, 315 (1986).Google Scholar
13. Rietman, E.A., Kaplan, M.L. and Cava, R.J., Solid State Ionics, 25, 41 (1986).Google Scholar
14. Li, G., Yang, Q., Fang, B., Hu, C. and Ying, S., in Recent Advances in Fast Ion Conducting Materials and Devices, edited by Chowdari, B.V.R., Liu, Q. and Chen, L. (World Scientific, Singapore, 1990), p. 295.Google Scholar
15. Teeters, D., Wong, M. and Straub, C.L., Solid State Ionics, 53-56, 1083 (1992).Google Scholar