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Competitive Phase Selection in Fe-Ni Alloy Droplets

Published online by Cambridge University Press:  21 February 2011

F. Gärtner ,
A. F. Norman ,
H. Assadi  and
A. L. Greer
F. Gärtner
Affiliation:
Department of Materials Science and Metallurgy, University of Cambridge, Pembroke Street, Cambridge, CB2 3QZ, U.K.
A. F. Norman
Affiliation:
Department of Materials Science and Metallurgy, University of Cambridge, Pembroke Street, Cambridge, CB2 3QZ, U.K.
H. Assadi
Affiliation:
Department of Materials Science and Metallurgy, University of Cambridge, Pembroke Street, Cambridge, CB2 3QZ, U.K.
A. L. Greer
Affiliation:
Department of Materials Science and Metallurgy, University of Cambridge, Pembroke Street, Cambridge, CB2 3QZ, U.K.
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Abstract

In the solidification of Fe-Ni droplets (≤ 30 at.% Ni), the selection of different microstructures is dominated by the competition between the bcc and ccp phases. In drop-tube experiments ccp is the primary phase in some dilute (up to 7at% Ni) alloys although the bcc phase is favoured by a lower free energy and by a lower interfacial energy with the liquid. Competitive dendrite growth is a possible explanation for the formation of primary ccp. Comprehensive thermodynamic (CALPHAD) and kinetic modelling is undertaken to understand the growth competition. The origin of the observed primary phases is discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 398: Symposium C – Thermodynamics and Kinetics of Phase Transformations , 1995 , 51
Copyright
Copyright © Materials Research Society 1998

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References

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