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Comparison of Surface Layers Formed on Synthetic Basaltic Glass, French R7T7 and HMI Borosilicate Nuclear Waste form Glasses - Materials Interface Interactions Tests, Waste Isolation Pilot Plant

Published online by Cambridge University Press:  21 February 2011

Michael J. Jercinovic ,
Stacy A. Kaser ,
Rodney C. Ewing  and
Werner Lutze
Michael J. Jercinovic
Affiliation:
Department of Geology, University of New Mexico, Albuquerque, NM 87131
Stacy A. Kaser
Affiliation:
Department of Geology, University of New Mexico, Albuquerque, NM 87131
Rodney C. Ewing
Affiliation:
Department of Geology, University of New Mexico, Albuquerque, NM 87131
Werner Lutze
Affiliation:
Hahn Meitner Institut, Berlin GmbH, Glienicker Straβe, 1000 Berlin 39, F.R., Germany
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Abstract

Materials Interface Interaction Test results for up to 2 years indicate that surface layers formed on synthetic basaltic glass in brine are predominantly Mg-chloride or oxychloride. Layers formed on HMI and R7T7 borosilicate glass are Mg-silicates. Layer thickness increases from 1 year to 2 years for basaltic glass and HMI borosilicate glass. Mg-silicate contains Ni and Zr in amounts that are generally related to the composition of associated glass, but layers formed on basaltic glass also contain Ni and Zr, elements not present in the glass. Ni and Zr are, in part externally derived, however, Ti appears to be completely immobile, and is not found in layers formed on Ti-free glass (R7T7). Some chemical components of the surface layers are derived, in part, from alteration of glass but major components of the layers are from the brine.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 176: Symposium U – Scientific Basis for Nuclear Waste Management XIII , 1989 , 355
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

1 Wicks, G.G. and Molecke, M.A., in Proceedings of the Workshop on Testing of High Level Waste Forms Under Repository Conditions, to be published as EUR 12 017 EN in 1989, The Commission of The European Communities.Google Scholar
2 Molecke, M.A., in Proceedings of the Workshop on Testing of High Level Waste Forms Under Repository Conditions, to be published as EUR 12 017 EN in 1989, The Commission of The European Communities.Google Scholar
3 Barkatt, A., Macedo, P.B., Gibson, B.C., and Montrose, C.J., in Scientific Basis for Nuclear Waste Management VIII, (Materials Research Society, Pittsburgh, PA., 1985), p. 5.Google Scholar
4 Grambow, B., in Scientific Basis for Nuclear Waste Management, Vol. IX, (Materials Research Society, Pittsburgh, PA., 1985), p. 263.Google Scholar
5 Harvey, K.B. and Litke, C.D., J. Amer. Cer. Soc. 67, 553 (1984).Google Scholar
6 Pescatore, C. and Machiels, A.J., in Advances in Ceramics VIII. Nuclear Waste Management, (Amer. Cer. Soc., Columbus, OH., 1983), p. 509.Google Scholar
7 Jercinovic, M.J. and Ewing, R.C., Basaltic Glasses from Iceland and the Deep Sea: Natural Analogues to Borosilicate Nuclear Waste-Form Glass, JSS Project Technical Report 88-01, (SKB, Stockholm, 1987).Google Scholar
8 Ewing, R.C. and Jercinovic, M.J., in Scientific Basis for Nuclear Waste Management, Vol. X, (Materials Research Society, Pittsburgh, PA., 1987), p. 67.Google Scholar
9 Jercinovic, M.J. and Keil, K., in Microbeam Analvsis-1988, (San Francisco Press, Inc., San Francisco, 1988), p. 495.Google Scholar
10 Chamber, W.F., SANDIA TASK8. A Subroutined Electron Microprobe Automation System, Sandia Laboratories Research Report SAND85-2037, (1985).Google Scholar
11 Vernaz, E. and Godon, N., in Proceedings of the Workshop on Testing of High Level Waste Forms Under Repository Conditions, to be published as EUR 12 017 EN in 1989, The Commission of The European Communities.Google Scholar
12 Jantzen, C.M., Clarke, D.R., Morgan, P.E.D., and Harker, A.B., J. Amer. Cer. Soc., 65, 292 (1982).Google Scholar
13 Harker, A.B., Flintoff, J.F., and Howitt, D.G., in Proceedings of the Workshop on Testing of High Level Waste Forms Under Repository Conditions, to be published as EUR 12 017 EN in 1989, The Commission of The European Communities.Google Scholar
14 Jercinovic, M.J., Kaser, S.A., and Ewing, R.C., in Proceedings of the Fourth International Symposium on Ceramics in Nuclear Waste Management, Amer. Ceramic Society Annual Meeting, 1989, in press.Google Scholar
15 Jercinovic, M.J., Kaser, S.A., and Ewing, R.C., Observations of Surface Layers Formed on HMI Borosilicate Glass: 6 Month. I Year, and 2 Year MIIT Experiments, Unpublished Report to the Hahn Meitner Institute, (1989).Google Scholar
16 Molecke, M.A., Sorensen, N.R., and Krumhansl, J.L., in Proceedings of the Workshop on Testing of High Level Waste Forms Under Repository Conditions, to be published as EUR 12 017 EN in 1989, The Commission of The European Communities.Google Scholar