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The Ceramist as Chemist - Opportunities for New Materials

Published online by Cambridge University Press:  15 February 2011

D. R. Uhlmann
Affiliation:
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Mass. 02139
B.J.J. Zelinski
Affiliation:
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Mass. 02139
G.E. Wnek
Affiliation:
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Mass. 02139
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Abstract

The use of sol-gel techniques to prepare glasses and crystalline ceramics offers outstanding opportunity for breakthroughs in technology. The areas of particular promise include novel glasses; crystallineceramics with exceptional microstructures; coatings for modification of electrical, optical, mechanical and chemical properties; porous media with high surface area and tailored chemistry; ceramic powders with high chemical homogeneity and narrow distributions of particle size; matrix materials in ceramicceramic composites; and a wide spectrum of specialty ceramic materials, ranging from abrasives and fibers to glass ceramics and films. Opportunities in each of these areas will be discussed and related to the advances in understanding and process technology required for their achievement. The theses will be advanced that creative chemistry provides the key to many of these advances, that ceramists simply MUST learn more chemistry, but that we dare not rest from our labors when the chemistry is done.

Type
Research Article
Copyright
Copyright © Materials Research Society 1984

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References

REFERENCES

1. Prochazka, S. and Klug, F.J., J. Am. Ceram. Soc., 66, 874 (1983).CrossRefGoogle Scholar
2. Barringer, E.A. and Bowen, H.K., J. Am. Ceram. Soc., 65, C199 (1982).CrossRefGoogle Scholar
3. Kamiya, K., Sakka, S. and Tatemichi, Y., J. Mater. Sci., 15, 1765 (1980).CrossRefGoogle Scholar
4. Hayashi, T. and Saito, H., J. Mater. Sci., 15, 1971 (1980).Google Scholar
5. Sowman, H.G., and Leitheiser, M.A.: U.S. Patent, 4,314,827 (1982).Google Scholar
6. Oak Ridge National Lab. development reported in Am. Ceram. Soc. Bull., 62, 1089 (1983).Google Scholar
7. de Monterey, F., “Passivation Coatings on Glass for Liquid Crystal Displays,” private communication.Google Scholar
8. Dislich, H., “Coatings on Glass,” Treatise on Glass, 2, Uhlmann, D.R. and Kreidl, N.J., eds. (Academic Press Inc., 1984).Google Scholar
9. Brinker, C.J. and Harrington, M.S., Solar Energy Materials, 5, 159 (1981).CrossRefGoogle Scholar
10. Mahler, W. and Bechtold, M.F., Nature, 285, 27 (1980).CrossRefGoogle Scholar
11. Sakka, S., “Formation of Glass and Amorphous Oxide Fibers from Solution,” the Proceedings.Google Scholar
12. Philipp, G. and Schmidt, H., “New Materials for Contact Lenses Prepared from Si and Ti Alkoxides by the Sol-Gel Process,” to be published in J. Non-Cryst. Solids; H. Schmidt “Organically Modified Silicates by the Sol-Gel Process,” this Proceedings.Google Scholar
13. Russo, W.R. and Nelson, W.H., J. Amer. Chem. Soc., 92, 152 (1970).Google Scholar
14. Bradley, D.C., Mehrotra, R.C. and Gaur, D.P., Metal Alkoxides (Academic Press Inc., London, 1978).Google Scholar
15. Meerwein, H. and Bersin, T., Ann., 476, 113 (1929).Google Scholar
16. Govil, S. and Mehrotra, R.C., Syn. React. Inorg. Metal-Org. Chem., 5, 267 (1975).Google Scholar
17. Novaselova, A.V., Ya. Turova, N., Turevskaya, E.P., Yanovskaya, M.I., Kozunov, V.A., and Kozlova, N.I., Izv. Akad. Nauk SSSR, Neorgan. Materialy, 15, 1055 (1979).Google Scholar
18. Emeléus, H.J. and Sharpe, A.G., Modern Aspects of Inorganic Chemistry, 4th ed., Chp. 10 (Wiley, New York 1973).Google Scholar
19. Gimblatt, F.G.R., Inorganic Polymer Chemistry, Chaps. 3 and 4 (Butterworths, London, 1963).Google Scholar
20. Schaefer, D.W., “Structure of Soluble Silicates,” this Proceedings.Google Scholar
21. Di Filippo, G.V., Ph.D. Thesis, Massachusetts Institute of Technology, Cambridge, Mass. (1983).Google Scholar
22. Mukherjee, S.P., “Homogeneity of Gels and Gel-Derived Glasses,” to be published in J. Non-Cryst. Solids.Google Scholar
23. Schmidt, H., Scholze, M. and Kaiser, A., J. Non-Cryst. Solids, 48, 65 (1982).Google Scholar
24. Yoldas, B.E., “Modification of Polymer-Gel Structures”, to be published in J. Non-Cryst. Solids.Google Scholar
25. Yamane, M., Inoue, S. and Nakazawa, K., J. Non-Cryst. Solids, 48, 153 (1982).Google Scholar
26. Tanaka, T., Sci. Am., 244, 124 (1981).CrossRefGoogle Scholar
27. Mukherjee, S.P. and Zarzycki, J., J. Non-Cryst. Solids, 20, 455 (1976).Google Scholar
28. Weinberg, M.C. and Neilson, G.F., J. Am. Ceram. Soc., 66, 132 (1983).Google Scholar
29. Weinberg, M.C. and Neilson, G.F., J. Mater. Sci., 13, 1206 (1978).CrossRefGoogle Scholar
30. Yoldas, B.E., Ceramics and Glasses, 105 (1981).Google Scholar
31. Hench, L.L., “Environmental Effects in Gel-Derived Materials,” this Proceedings.Google Scholar