Hostname: page-component-84b7d79bbc-fnpn6 Total loading time: 0 Render date: 2024-07-25T22:45:34.237Z Has data issue: false hasContentIssue false

Band-Offset Determination for Intrinsic a-Si/ p+ μc-Si or Intrinsic a-Si/n+ νc-Si Heterostructure

Published online by Cambridge University Press:  10 February 2011

Hong Zhu
Affiliation:
Electronic Materials and Processing Research Laboratory, The Pennsylvania State University, 227 Hammond Bldg, University Park, PA 16802
Stephen J Fonash
Affiliation:
Electronic Materials and Processing Research Laboratory, The Pennsylvania State University, 227 Hammond Bldg, University Park, PA 16802
Get access

Abstract

The conduction band ΔEc and valance band ΔEv, off-sets at interfaces are critical parameters for device simulation. With the transport simulation code AMPS we demonstrate the possibility of using an analysis of the far forward I-V characteristics versus temperature for i- layer /n+ or i-layer /p+ hetero structures to obtain ΔEc or AE., respectively. For example, if one wants to extract AE, from experimental data for the interface a-Si/uc n+ Si interface, we show this can be done using a metal/intrinsic a-Si:H/uc n+ Si structure. With proper choice of the metal, the hole barrier height at the metal can be made large enough that the far forward current is only carried by electrons. We have found that, with the proper choice of structure thickness this far forward current can be controlled by ΔEc and not by space charge limited current. Unlike the work of Arnold et al [1], we have found that the choice of structure thickness is critical. In this case of an a-Si/uc n+ structure this far forward current is actually controlled by ΔEC+ΔVn where ΔVn is the activation energy in the n+ uc-Si layer. Since ΔVn can typically be ∼ 0.05eV in uc-Si, we see that ΔEc is essentially controlling this far forward current. To demonstrate the approach for the case of an a-Si/uc n+ Si interface we consider different i-layer thicknesses.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1 Arnold, D., Ketterson, A., Henderson, T. Appl. Phys. Lett. 45, 1237 (1984)Google Scholar
2 Guha, S, Yang, J., Nath, P., and Hack, M. Enhancement of open circuit voltage in high efficiency amorphous silicon alloy solar cells Appl. Phys. Lett 49(4) 28 July P218 (1986)Google Scholar
3 Locovsky, G. and Barrier, C. Wang limited transport mechnisms in doped uc-Si and uc-Si.C Mat Res Soc Symp Proc Vol 219 P377 (1991)Google Scholar
4 Lee, Y Ph.D Thesis 1998 the Penn State UniversityGoogle Scholar
5 Heller, David E Master thesis Electronic transport mechanisms of Schottky barrier contacts on amorphous silicon thin films 1991 the Penn State University Google Scholar
6 Xu, X., Yang, J., Banejee, A., and Guha, S., Vasanth, K. and Wagner, S Band edge discontinuities between microcrystalline and amorphous hydrogenated silicon alloys and their effect on solar cell performance Appl Phys Lett 67(16) Oct P2323 (1995)Google Scholar
7 Guh, S.a Amorphous Silicon Research: PhaseH: Anunual Technical Progress Report lAug 1995-31 July 1996 Google Scholar