Hostname: page-component-848d4c4894-sjtt6 Total loading time: 0 Render date: 2024-07-01T13:55:07.509Z Has data issue: false hasContentIssue false
  • English
  • Français

Anatase Inverse Opal: Preparation and Electrochemical Properties

Published online by Cambridge University Press:  15 March 2011

Marketa Zukalova ,
Martin Kalbac ,
Ladislav Kavan  and
J. Heyrovsky
Marketa Zukalova
Affiliation:
Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejskova 3, CZ-182 23, Prague 8, Czech Republic
Martin Kalbac
Affiliation:
Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejskova 3, CZ-182 23, Prague 8, Czech Republic
Ladislav Kavan
Affiliation:
Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejskova 3, CZ-182 23, Prague 8, Czech Republic
J. Heyrovsky
Affiliation:
Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejskova 3, CZ-182 23, Prague 8, Czech Republic
Get access

Abstract

Anatase inverse opal was synthesized both in the powder form and in the thin layer by means of templating with latex spheres. The voids between close-packed latex particles were filled via deposition from the titanium (IV) isopropoxide solution, electrochemical deposition from the solution of TiCl3, and liquid phase deposition from the (NH4)2TiF6 solution. The resulting material exhibited a regular fcc ordering of macropores surrounded with the framework consisting of the anatase nanocrystallites of 20 nm in size. Electrochemical performance for lithium insertion of anatase inverse opal was sluggish compared to that of non-templated anatase with more dense packing of nanocrystals.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 820: Symposia O/R – Nanoengineered Assemblies and Advanced Micro/Nanosystems , 2004 , R5.3
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Schroden, R. C.; Al-Daous, M.; Blanford, C. F.; Stein, A. Chem.Mater. 2002, 14 3305–3315.Google Scholar
2. Stein, A.; Schroden, R. C. Current Opinion in Solid State and Material Science 2001, 5 553–564.Google Scholar
3. Johnson, N. P.; McComb, D. W.; Richel, A.; Treble, B. M.; De La Rue, R. M. Synthetic Metals 2001, 116 469–473.Google Scholar
4. Gu, Z. Z.; Kubo, S.; Fujishima, A.; Sato, O. Appl.Phys.A 2002, 74 127–129.Google Scholar
5. Holland, B. T.; Blanford, C. F.; Stein, A. Science 1998, 281 538–540.Google Scholar
6. Nishimura, S.; Abrams, N.; Lewis, B. A.; Halaoui, L. I.; Mallouk, T. E.; Benkstein, K. D.; Van de Langemaat, J.; Frank, A. J. Journal of the American Chemical Society 2003, 125 6306–6310.Google Scholar
7. Kavan, L.; O'Regan, B.; Kay, A.; Grätzel, M. Journal of Electroanalytical Chemistry 1993, 346 291–307.Google Scholar
8. Nishimura, S.; Shishido, A.; Abrams, N.; Mallouk, T. E. Appl.Phys.Lett. 2002, 81 4532–4534.Google Scholar