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X-ray Absorption Spectroscopy Investigation of the Sub-Nanoscale Strain in Thin-Film Lithium Ion Battery Cathodes

Published online by Cambridge University Press:  03 September 2012

Faisal M. Alamgir ,
Jason Vansluytman ,
Daniel Carter ,
Jay Whitacre ,
Chi-Chang Kao ,
Steve Greenbaum  and
Marten Denboer
Faisal M. Alamgir
Affiliation:
Physics and Astronomy Department, Hunter College of the City of New YorkNew York, NY 10021, U.S.A. National Synchrotron Light Source, Brookhaven National Laboratory, Upton, NY
Jason Vansluytman
Affiliation:
Physics and Astronomy Department, Hunter College of the City of New YorkNew York, NY 10021, U.S.A.
Daniel Carter
Affiliation:
Physics and Astronomy Department, Hunter College of the City of New YorkNew York, NY 10021, U.S.A.
Jay Whitacre
Affiliation:
Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA
Chi-Chang Kao
Affiliation:
National Synchrotron Light Source, Brookhaven National Laboratory, Upton, NY
Steve Greenbaum
Affiliation:
Physics and Astronomy Department, Hunter College of the City of New YorkNew York, NY 10021, U.S.A.
Marten Denboer
Affiliation:
Physics and Astronomy Department, Hunter College of the City of New YorkNew York, NY 10021, U.S.A.
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Abstract

LiCoO2 and LiNiO2, two important cathode materials for Li-ion batteries, were studied in their respective bulk and thin-film form. X-ray absorption spectroscopy (XAS) has been used to probe the local atomic structure and structural defects in the thin-film and bulk cathodes. Results comparing Li(Co,Ni)O2 in the bulk and thin-film forms suggests a correlation between intrinsic stress and local strain in the thin-film. This local strain is manifested by a collapse of the six-fold rotational symmetry within the metal-metal layer of the Li(Co,Ni)O2 system into a two fold one. The relationship between annealing conditions and the resulting local strain in these films is examined.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 822: Symposium S – Nanostructured Materials in Alternative Energy Devices , 2004 , S2.3
Copyright
Copyright © Materials Research Society 2004

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References

1 Aragon, A. Martinez de, J. Micromech. Microeng. 8, 54–56 (1998).Google Scholar
2 West, W. C., Whitacre, J. F., White, V., Ratnakumar, B. V., J. Micromechanics and Microengineering 12, 58 (2002).Google Scholar
3 RC, T. I. Van Landschoot, Schoonman, J., Solid State Ionics 160, no.3-4, pp.271–9 (2003).Google Scholar
4 Zhang, Y. C., Wang, Hao, Xu, Hai Yan, Wang, Bo, Yan, Hui, Ahniyaz, A, Yoshimura, M., Solid State Ionics 158, no.1-2, pp.113–17 (2003).Google Scholar
5 Hart, R. W., White, H. S., Dunn, B., Rolison, D. R.. 3-D microbatteries. Electrochemistry Communications 5, no.2, pp.120–3 (2003).Google Scholar
6 Wang, B., Bates, J. B., Hart, F. X., Sales, B.C., Zuhr, R. A., and Robertson, J. D., J. Electrochem. Soc. 143, 10, 3203 (1996).Google Scholar
7 Whitacre, J. F., West, W. C., Brandon, E., and Ratnakumar, B. V. J. Electrochem. Soc. 148, A1078 (2001).Google Scholar
8 Alamgir, F. M., Ito, Y., Jain, H., and Williams, D. B., Phil. Mag Lett. 81, 3, 213–222 (2001).Google Scholar
9 Ankudinov, A. L., Ravel, B., Rehr, J. J., and Conradson, S.D., Phys. Rev. B 7565 (1998).Google Scholar