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Synthesis and Structural Characterization of Organically-Modified Microporous Silicates

Published online by Cambridge University Press:  10 February 2011

F. Babonneau ,
L. Leite ,
S. Fonlupt ,
F. Ribot ,
L. Bergogne  and
C. Roux
F. Babonneau
Affiliation:
Université Pierre et Marie Curie / CNRS, Chimie de la Matière Condensée, Paris, France
L. Leite
Affiliation:
Université Pierre et Marie Curie / CNRS, Chimie de la Matière Condensée, Paris, France
S. Fonlupt
Affiliation:
Université Pierre et Marie Curie / CNRS, Chimie de la Matière Condensée, Paris, France
F. Ribot
Affiliation:
Université Pierre et Marie Curie / CNRS, Chimie de la Matière Condensée, Paris, France
L. Bergogne
Affiliation:
Université Pierre et Marie Curie / CNRS, Chimie de la Matière Condensée, Paris, France
C. Roux
Affiliation:
Université Pierre et Marie Curie / CNRS, Chimie de la Matière Condensée, Paris, France
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Abstract

Organically-modified silicates have been synthesized from RSi(OEt)3 (R = CH3, C2H5, C8H17, CH2=CH, C6H5) and TEOS under acidic conditions, in the presence of cethyltrimethylammonium (CTAB). The introduction of RSiO1.5 units with R/Si =0.2, affects the ordering of the expected hexagonal silicate phase, except when R = C6H5. The sample containing phenyl functions was thus submitted to surfactant extraction; calcination at 350°C appears to be more efficient, and less disruptive for the network ordering than a washing procedure in ethanol. Nitrogen adsorption measurements on the hexagonally ordered calcined sample that still contains phenyl groups, yields a type I isotherm, typical of a microporous solid. BET method leads to a surface area of 1000 m2/g and a pore volume of 0.32 cm3/g.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 519: Symposium O – Organic/Inorganic Hybrid Materials , 1998 , 363
Copyright
Copyright © Materials Research Society 1998

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References

1 Beck, J.S., Vartuli, J.C., Roth, W.J., Leonowicz, M.E., Kresge, C.T., Schmitt, K.D., Chu, C.T-W., Olson, D. H., Sheppard, E.W., McCullen, S.B., Higgins, J.B., Schlenker, J.L., J. Am. Chem. Soc. 114, 10834 (1992).10.1021/ja00053a020Google Scholar
2 Sayari, A., Chem. Mater. 8, 1840 (1996).10.1021/cm950585+Google Scholar
3 Sutra, P., Brunel, D., J. Chem. Soc. Chem. Comm.Google Scholar
4 Mercier, L. and Pinnavaia, T.J., Adv. Mater. 9, 500 (1997).Google Scholar
5 Liu, J., Feng, X., Fryxell, G.E., Wang, L.-Q., Kim, A.Y., Gong, M., Adv. Mater., 10, 161 (1998).Google Scholar
6 Burkett, S.L., Sims, S.D., Mann, S., J. Chem. Soc. Chem. Comm. 1367 (1996)Google Scholar
7 Fowler, C.E., Burkett, S.L., Mann, S., J. Chem. Soc. Chem. Comm. 1769 (1997)Google Scholar
8 Macquarrie, D.J., J. Chem. Soc. Chem. Comm. 1961 (1996)Google Scholar
9 Macquarrie, D.J., J. Chem. Soc. Chem. Comm. 1781 (1997)Google Scholar
10 Lim, M. H., Blanford, C.F., Stein, A., J. Am. Chem. Soc. 119, 4090 (1997).10.1021/ja9638824Google Scholar
11 Lim, M. H., Blanford, C.F., Stein, A., Chem. Mater. 10, 467 (1998).10.1021/cm970713pGoogle Scholar
12 Tavev, P.T., Pinnavaia, T.J., Science, 267, 865 (1995).Google Scholar
13 Schmidt, H., Scholze, H., Kaiser, A., J. Non Cryst. Solids 63, 1 (1984).Google Scholar
14 Huo, Q., Margolese, D.I., Stucky, G.D., Chem. Mater. 8, 1147 (1996).10.1021/cm960137hGoogle Scholar
15 Delattre, L., Babonneau, F., Mat. Res. Soc. Symp. Proc. 346, 365 (1994)10.1557/PROC-346-365Google Scholar
16 Barrett, E.P., Joyner, L.G., Halenda, P.H., J. Am. Chem. Soc. 73, 373 (1951)Google Scholar