Hostname: page-component-77c89778f8-gq7q9 Total loading time: 0 Render date: 2024-07-18T16:07:23.105Z Has data issue: false hasContentIssue false
  • English
  • Français

Sr(Ti,Fe)O3: Materials for a Temperature Independent Resistive Oxygen Sensor

Published online by Cambridge University Press:  15 February 2011

W. Menesklou ,
H.-J. Schreiner ,
R. Moos ,
K.H. Härdtl  and
E. Ivers-Tiffée
W. Menesklou
Affiliation:
×Universität Karlsruhe (TH), Institut für Werkstoffe der Elektrotechnik, Germany, wolfgang.menesklou@etec.uni-karlsrnhe.de
H.-J. Schreiner
Affiliation:
×Universität Karlsruhe (TH), Institut für Werkstoffe der Elektrotechnik, Germany, wolfgang.menesklou@etec.uni-karlsrnhe.de
R. Moos
Affiliation:
DaimlerChrysler Research, Friedrichshafen, Germany
K.H. Härdtl
Affiliation:
×Universität Karlsruhe (TH), Institut für Werkstoffe der Elektrotechnik, Germany, wolfgang.menesklou@etec.uni-karlsrnhe.de
E. Ivers-Tiffée
Affiliation:
×Universität Karlsruhe (TH), Institut für Werkstoffe der Elektrotechnik, Germany, wolfgang.menesklou@etec.uni-karlsrnhe.de
Get access

Abstract

The metal oxide strontium titanate is a promising material for resistive high temperature oxygen sensors (T > 1000 K), that can be applied to control combustion engines. However, a disadvantage of this and of many other metal oxides is the strong temperature dependence of conductivity. In this work, we show that the temperature dependence of Sr(Ti1-x, Fex)O3-δ can be adjusted by the iron content. For x = 0.35 the thermal activation of the conductivity is near zero for a distinct temperature and oxygen partial pressure range (T = 1000 K - 1200 K, PO2 = 10 to 105 Pa). Short response times in the range of 10 ms can be realized by using sensors in thick film technology

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 604: Symposium LL – Materials for Smart Systems III , 1999 , 305
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

references

1 Logothetis, E.M. in Ceramic Engineering & Science, Proceedings 1, Westerville, Ohio (1980) pp. 281–301.Google Scholar
2 Moseley, P.T., Sensors and Actuators B 6, 149–156 (1992).10.1016/0925-4005(92)80047-2Google Scholar
3 Park, K., Logothetis, E.M., J. Electrochem. Soc.: Solid-State Science and Technology 124 (9), 1443–46 (1977).10.1149/1.2133671Google Scholar
4 Yu, C., Shimizu, Y., Arai, H., Chemistry Letters, 563–566 (1986).10.1246/cl.1986.563Google Scholar
5 Moseley, P.T., Williams, D.E., Polyhedron 8 (13/14), 1615–18 (1989).10.1016/S0277-5387(00)80606-3Google Scholar
6 Williams, D.E., Tofield, B.C., McGeehin, P., European Patent Specification EP0062994 (1982).Google Scholar
7 Moos, R., Menesklou, W., Schreiner, H.J., Hdrdtl, K.H., Materials for temperature independent resistive oxygen sensors for combustion gas control, to be published in Sensors and Actuators B.10.1016/S0925-4005(00)00421-4Google Scholar
8 Beetz, K., Die geschlossene Festelektrolyt-Sauerstoffpumpe, Fortschr.-Ber. VDI 8 (358) Düsseldorf (1993). Ph.D. thesis.Google Scholar
9 Tragut, Ch., Kinetik schneller Sauerstoffsensoren, Fortschr.-Ber. VDI 8 (291) Düsseldorf (1992). Ph.D. thesis.Google Scholar
10 Tragut, Ch., Härdtl, K.H., Sensors and Actuators B 4, 425–429 (1991).10.1016/0925-4005(91)80146-BGoogle Scholar
11 Moos, R., Härdtl, K.H., J. Am. Ceram. Soc. 80 (10), 2549–62 (1997).10.1111/j.1151-2916.1997.tb03157.xGoogle Scholar
12 Menesklou, W., Schreiner, H.-J., Härdtl, K.H. and Ivers-Tiffée, E., Sensors and Actuators B 59/2-3, 184–189 (1999).10.1016/S0925-4005(99)00218-XGoogle Scholar
13 Schreiner, H.-J., Temperaturunabhängige resistive Sauerstoffsensoren auf der Basis von Sr(Ti, Fe)O3-δ, Ph.D. thesis, Karlsruhe (1999).Google Scholar
14 Steinsvik, S., Bugge, R., Gjonnes, J., Tafto, J., Norby, T., J. Phys. Chem. Solids 58 (6), 969–76 (1997).10.1016/S0022-3697(96)00200-4Google Scholar
15 Waser, R., J. Am. Ceram. Soc. 74 [8], 1934–40 (1991).10.1111/j.1151-2916.1991.tb07812.xGoogle Scholar
16 Lampe, U., Gerblinger, J., Meixner, H., Sensors and Actuators B 7, 787–91 (1992).10.1016/0925-4005(92)80404-LGoogle Scholar
17 Lampe, U., Fleischer, M., Reitmeier, N., Meixner, H., McMonagle, J.B., Marsh, A., New Metal Oxide Sensors: Materials and Properties, in Sensors Update 2, edited by Baltes, H., Göpel, W., Hesse, J. (VCH Verlagsgesellschaft, Weinheim, 1996) pp.1–36.Google Scholar