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Role of Hydrogen for Microcrystalline Silicon Formation

Published online by Cambridge University Press:  10 February 2011

K. Saitoh
Affiliation:
TFSSC Superlab., Electrotechnical Laboratory, Tsukuba, Japan
M. Kondo
Affiliation:
TFSSC Superlab., Electrotechnical Laboratory, Tsukuba, Japan Tokyo Institute of Technology, Yokohama, Japan
M. Fukawa
Affiliation:
TFSSC Superlab., Electrotechnical Laboratory, Tsukuba, Japan
T. Nishimiya
Affiliation:
TFSSC Superlab., Electrotechnical Laboratory, Tsukuba, Japan
W. Futako
Affiliation:
Tokyo Institute of Technology, Yokohama, Japan
I. Shimizu
Affiliation:
Tokyo Institute of Technology, Yokohama, Japan
A. Matsuda
Affiliation:
TFSSC Superlab., Electrotechnical Laboratory, Tsukuba, Japan Tokyo Institute of Technology, Yokohama, Japan
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Abstract

The role of hydrogen atoms in the formation process of hydrogenated microcrystalline silicon (μc-Si:H) by plasma enhanced chemical vapor deposition method has been investigated. Under the present conditions, the etching and the permeation of hydrogen atoms in the subsurface region do not cause the crystallization. The kinetics study of surface morphology and structure in the initial growth of μc-Si:H on an atomically flat substrate indicates that the onset thickness of island coalescence reduced under μc-Si:H formation condition. The results support the ‘surface diffusion model’ in which the surface diffusion of film precursors is enhanced by the sufficient hydrogen coverage of surface and by hydrogen atom recombination energy on the growing surface of the film.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

1 Meier, J., Torres, P., Platz, R., Dubail, S., Kroll, U., Selvan, J.A. Anna, Vaucher, N. Pellaton, Hof, Ch., Fischer, D., Keppner, H., Shah, A., Ufert, K.-D., Giannoules, P. and Koehler, J., Mat. Res. Soc. Symp. Proc. 420, (1996) pp.314 Google Scholar
2 Matsuda, A., J. Non-Cryst. Solids 59 & 60 (1983) 767774 Google Scholar
3 Tsai, C.C., Anderson, G.B., Thompson, R. and Wacker, B., J. Non-Cryst. Solids 114, (1989) 151153 Google Scholar
4 Shibata, N., Fukuda, K., Ohtoshi, H., Hanna, J., Oda, S. and Shimizu, I., Mat. Res. Soc. Symp. Proc. 95, (1987) pp.225235 Google Scholar
5 Nakamura, K., Yoshino, K., Takeoka, S. and Shimizu, I., Jpn. J. Appl. Phys. Vol. 34 (1995) pp. 442449 Google Scholar
6 Veprek, S. and Maracek, V., Solid State Electron. 11 (1968) 683684 Google Scholar
7 Asano, A., T. Ichimura and Sakai, H., J. Appl. Phys. 65 (1989) 24392444 Google Scholar
8 Asano, A., Appl. Phys. Lett. 56 (1990) 533535 Google Scholar
9 Nguyen, H.V., An, I., Collins, R.W., Lu, Y., Wakagi, M. and Wronski, C.R., Appl. Phys. Lett. 65 (1994) 33353337 Google Scholar
10 Karpenko, O. P., Yalisove, S. M. and Eaglesham, D.J., J. Appl. Phys. 82, (1997), pp.11571165 Google Scholar
11 Matsuda, A. and Goto, T., Mat. Res. Soc. Symp. Proc. 164, (1989) pp. 314 Google Scholar
12 Saitoh, K., Kondo, M., Fukawa, M., Nishimiya, T., Matsuda, A., Futako, W. and Shimizu, I., Appl. Phys. Lett. 71 (1997) 34033405 Google Scholar
13 Gerard, P., Deneuville, A. and Courths, R., Thin Solid Films 71 (1980) 221 Google Scholar
14 Kondo, M., Nishimiya, T., Saitoh, K., Ohe, T. and Matsuda, A., Mat. Res. Soc. Symp. Proc. 467, (1997) pp.391396 Google Scholar
15 Saitoh, K., Kondo, M. and Matsuda, A., Mat. Res. Soc. Symp. Proc. 467, (1997) pp.385390 Google Scholar