Hostname: page-component-7479d7b7d-rvbq7 Total loading time: 0 Render date: 2024-07-13T16:17:47.641Z Has data issue: false hasContentIssue false
  • English
  • Français

The Reaction of SRL 202 Glass in J-13 and DIW

Published online by Cambridge University Press:  01 January 1992

W. L. Ebert ,
J. K. Bates  and
E. C. Buck
W. L. Ebert
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439-4837
J. K. Bates
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439-4837
E. C. Buck
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439-4837
Get access

Abstract

Static leach tests were performed in both 304L stainless steel and Teflon vessels using a synthetic high-level waste glass with either deionized water (DIW) or a tuff groundwater solution as the leachant to assess the effects of the vessel and the initial leachant composition on the extent and nature of the glass reaction. The tests were performed using monolith samples at 340 m−1 and crushed samples at 2000 m−1 for times up to 1 year. The results show less silicon is released from the glass into the groundwater solution than into DIW at both high and low glass surface area/leachant volume ratios (SA/V), but the alkali metal and boron releases are not affected by the leachant used. Tests performed in a stainless steel vessel resulted in slightly lower leachate pH values, but similar reaction rates to those performed in a Teflon vessel, as measured by the boron release. Blank tests with DIW or EJ-13 in the vessels showed the Teflon vessels to release small amounts of fluoride (1 to 2 ppm) and to acidify the DIW slightly (4.0 < pH < 5.6). The pH values of blank tests with EJ-13 increased from 8.2 to about 8.6 in steel and to about 9.2 in Teflon vessels. The slightly higher pH values attained in Teflon vessels are attributed to outgassing of CO2 during the test.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 294: Symposium V – Scientific Basis for Nuclear Waste Management XVI , 1992 , 137
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Ringwood, A.E., Kesson, S.L., Reeve, K.D., Levins, D.M. and Ramm, E.J., “Synroc” in Radioactive Wasteforms for the Future, editors Lutz, W. and Ewing, R.C., (North-Holland, Amsterdam, 1988) pp 233-334.Google Scholar
2. smith, K.I., Lumpkin, G.R., Blackford, M.G., Day, R.A. and Hart, K.P., J. Nucl Mat., 190, 287 (1992).Google Scholar
3. Dosch, R.G, Headley, T.J. and Hlava, P., J. Am. Ceram. Soc., 67, 354 (1984).Google Scholar
4. Morgan, P.E.D., Shaw, T.M. and Pugar, E.A., in Advances in Ceramics Vol.8, Nuclear Waste Management I. edited by Wicks, G.G and Ross, W.A., (American Ceramic Society, Columbus, OH, 1984) p. 234.Google Scholar
5. Harker, A.B. and Flintoff, J.F., in Advances in Ceramics Vol.8, Nuclear Waste Management I. edited by Wicks, G.G and Ross, W.A., (American Ceramic Society, Columbus, OH, 1984) p. 222.Google Scholar
6. Evans, J.P and Marples, J.A.C., “The Preparation of Fully Active Synroc and its Radiation Stability,” Rept. No. AERE-g 3592, AERE Harwell, Didcot, Oxfordshire, UK, 1985.Google Scholar
7. Kesson, S.E. and Ringwood, A.E., “Scientific Basis for Nuclear Wasre Management VII”. Edited by McVay, G.. Plenum Press, New York, 1984.Google Scholar
8. Dosch, R.G. and Lynch, A.W., “Solution Chemistry in Synroc Preparation,” Rept. No. SAND 80-2375, Sandia National Laboratory, Albuquerque, NM, 1980.Google Scholar
9. Xu, J.J., Shaikh, A. S., and Vest, R. W, IEEE Trans UFFC 36, 307 (1989).Google Scholar
10. Buykx, W.J., Hawkins, K., Levins, D.M., Seatonberry, B.W., Ryan, R.K., Hart, K.P., Stevens, G.T., Watson, K.G., Weedon, D., and White, T.J., J. Am. Ceram. Soc., 71, 678 (1988).Google Scholar
11. Meyer, V. and Janny, A., Berichte. 15 1525 (1882).Google Scholar
12. Reeve, K.D., Levins, D.M., Woolfrey, J.L. and Ramm, E.J., in Advances in Ceramics Vol.8, Nuclear Waste Management I. edited by Wicks, G.G and Ross, W.A., (American Ceramic Society, Columbus, OH, 1984) p. 201.Google Scholar