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Populations of Fluorine and Arsenic in AsF5-Graphite Intercalation Compounds

Published online by Cambridge University Press:  15 February 2011

H. Sfihi
Affiliation:
Laboratoire de Physique Quantique, ERA N°676E.S.P.C.I., 10, rue Vauquelin 75231 Paris Cedex 05, FRANCE
L. Facchini
Affiliation:
Laboratoire de Physique Quantique, ERA N°676E.S.P.C.I., 10, rue Vauquelin 75231 Paris Cedex 05, FRANCE
J. Bouat
Affiliation:
Laboratoire de Physique Quantique, ERA N°676E.S.P.C.I., 10, rue Vauquelin 75231 Paris Cedex 05, FRANCE
D. Bonnin
Affiliation:
Laboratoire de Physique Quantique, ERA N°676E.S.P.C.I., 10, rue Vauquelin 75231 Paris Cedex 05, FRANCE
A.P. Legrand
Affiliation:
Laboratoire de Physique Quantique, ERA N°676E.S.P.C.I., 10, rue Vauquelin 75231 Paris Cedex 05, FRANCE
G. Furdin
Affiliation:
Laboratoire de Chimle du Solide Minéiral, Service de Chimie Minerale Appliquee du Professeur Hérold, LA N°158, C.O. 140, 54037 Nancy Cedex, FRANCE
D. Billaud
Affiliation:
Laboratoire de Chimle du Solide Minéiral, Service de Chimie Minerale Appliquee du Professeur Hérold, LA N°158, C.O. 140, 54037 Nancy Cedex, FRANCE
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Abstract

19F nuclear magnetic resonance and As X-ray absorption results on AsF5-graphite intercalation compounds are discussed in terms of species of the commonly used oxidation reaction of the graphitic planes. Three fluorine populations and two oxidation states of the arsenic are clearly present, but they cannot be easily related to the oxidation reaction of the graphite planes.

Type
Research Article
Copyright
Copyright © Materials Research Society 1983

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References

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