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Phosphate Substituted Phosphazenes as Dispersants in Colloidal Ceramic Processing

Published online by Cambridge University Press:  25 February 2011

Sarah D. Burton ,
William D. Samuels  and
Gregory J. Exarhos
Sarah D. Burton
Affiliation:
Pacific Northwest Laboratory, Richland, WA 99352; JULIANN M. PLEVA, Saint Mary's College, Notre Dame IN, 46556
William D. Samuels
Affiliation:
Pacific Northwest Laboratory, Richland, WA 99352; JULIANN M. PLEVA, Saint Mary's College, Notre Dame IN, 46556
Gregory J. Exarhos
Affiliation:
Pacific Northwest Laboratory, Richland, WA 99352; JULIANN M. PLEVA, Saint Mary's College, Notre Dame IN, 46556
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Abstract

A new phosphate substituted phosphazene trimer [N3P3Cl5(OP(O)Ph2)] has been synthesized and characterized by 31p NMR and Raman spectroscopy. The course of each solution-state substitution was followed with 31P NMR, and this technique was used to determine the best reaction conditions for the experiment. Information such as phosphorus to phosphorus connectivity and purity were analyzed. This paper will discuss the synthesis and characterization of phosphazene moieties which are substituted by phosphorus(V) centered substituents.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 249: Symposium Q – Synthesis and Processing of Ceramics: Scientific Issues , 1991 , 267
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

[1] Samuels, W. D.; Exarhos, G. J.; Burton, S. D., Synthesis and Processing of Ceramics: Scientific Issues, 1991 Fall MRS Meeting Symposium Proceedings, Q.Google Scholar
[2] Exarhos, G. J.; Ferris, K. F.; Friedrich, D. M.; Samuels, W. D., Atomic and Molecular Processing of Electronic and Ceramic Materials: Preparation and Characterization, (Materials Research Society Proc., Pittsburgh, PA, 1988) 127.Google Scholar
[3] Di Gregorio, F.; , Marconi; W., , J. Org. Chem.. 1981, 46, 4569.Google Scholar
[4] Allcock, H. R., Phosphorus-Nitrogen Compound, Academic Press, New York and London, 1972.Google Scholar
[5] Quin, L. D., The Heterocyclic Chemistry of Phosphorus, J. Wiley and Sons. 1981.Google Scholar