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A Novel Method for Rapid Formation of High-ordered Self-Assembled Monolayer

Published online by Cambridge University Press:  01 February 2011

Yoshitaka Fujita
Affiliation:
Inorganic Materials Research Department, R. & D. Laboratory for High-Performance Materials, Nippon Soda Co., Ltd., 12–54 Goi-Minamikaigan, Ichihara, Chiba 290–0045, Japan
Norifumi Nakamoto
Affiliation:
Inorganic Materials Research Department, R. & D. Laboratory for High-Performance Materials, Nippon Soda Co., Ltd., 12–54 Goi-Minamikaigan, Ichihara, Chiba 290–0045, Japan
Hiroyuki Takeda
Affiliation:
Inorganic Materials Research Department, R. & D. Laboratory for High-Performance Materials, Nippon Soda Co., Ltd., 12–54 Goi-Minamikaigan, Ichihara, Chiba 290–0045, Japan
Tomoya Hidaka
Affiliation:
Inorganic Materials Research Department, R. & D. Laboratory for High-Performance Materials, Nippon Soda Co., Ltd., 12–54 Goi-Minamikaigan, Ichihara, Chiba 290–0045, Japan
Nobuo Kimura
Affiliation:
Inorganic Materials Research Department, R. & D. Laboratory for High-Performance Materials, Nippon Soda Co., Ltd., 12–54 Goi-Minamikaigan, Ichihara, Chiba 290–0045, Japan
Hiroshi Suzuki
Affiliation:
Inorganic Materials Research Department, R. & D. Laboratory for High-Performance Materials, Nippon Soda Co., Ltd., 12–54 Goi-Minamikaigan, Ichihara, Chiba 290–0045, Japan
Noriyuki Yoshimoto
Affiliation:
Graduate School of Engineering, Iwate University, 3–18–8 Ueda, Morioka, Iwate 020–8550, Japan
Satoshi Ogawa
Affiliation:
Faculty of Engineering, Iwate University, 3–18–8 Ueda, Morioka, Iwate 020–8550, Japan
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Abstract

We have discovered a novel chemisorption method using octadecyltrimethoxysilane (ODMS), titanium tetraisopropoxide (TTIP), water, and toluene [1] to form highly-ordered self-assembled monolayers (SAM) of ODMS. The SAMs were formed rapidly from the active solution even when it was kept for three months. The solution and layers were characterized by several methods. We propose a mechanism for the rapid formation of the ODMS-SAM.

Type
Research Article
Copyright
Copyright © Materials Research Society 2005

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References

1. Nakamoto, N., presented at the 51st Annual Meeting of Applied Physics, 3, 1356 (2004).Google Scholar
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9. We obtained monosilanol and its analogues by HPLC and NMR.Google Scholar

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