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Linear and Nonlinear Optical Properties of Novel Ionic Chromophores

Published online by Cambridge University Press:  21 March 2011

Xuan-Ming Duan
Affiliation:
Biopolymer Physics Laboratory, The Institute of Physical and Chemical Research (RIKEN), Hirosawa 2-1, Wako, Saitama 351-0198, Japan
Tatsuo Wada
Affiliation:
Biopolymer Physics Laboratory, The Institute of Physical and Chemical Research (RIKEN), Hirosawa 2-1, Wako, Saitama 351-0198, Japan
Shuji Okada
Affiliation:
Institute for Chemical Reaction Science, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan
Hidetoshi Oikawa
Affiliation:
Institute for Chemical Reaction Science, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan
Hiro Matsuda
Affiliation:
National Institute of Materials and Chemical Research, Higashi 1-1, Tsukuba, Ibaraki 305-8586, Japan
Hiroyuki Sasabe
Affiliation:
Biopolymer Physics Laboratory, The Institute of Physical and Chemical Research (RIKEN), Hirosawa 2-1, Wako, Saitama 351-0198, Japan
Hachiro Nakanishi
Affiliation:
Institute for Chemical Reaction Science, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan
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Abstract

A series of novel ionic chromophores consisting of a carbazole moiety and pyridinium rings connected by a double bond have been designed and synthesized as nonlinear optical materials. Their linear and nonlinear optical properties were investigated by semiempirical calculation and experiment. The absorption maximum wavelengths (lmax) of these ionic chromophores showed shifting to longer wavelength region than their corresponding electrically neutral compounds. These ionic chromophores possess large first hyperpolarizabilities (b).

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

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