Skip to main content Accessibility help
×
Home
Hostname: page-component-55597f9d44-t4qhp Total loading time: 0.295 Render date: 2022-08-14T23:06:34.747Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "useRatesEcommerce": false, "useNewApi": true } hasContentIssue true

Interface Stability between Ni-P film plated by Supercritical Electroless Plating and the Polymer Substrate

Published online by Cambridge University Press:  01 February 2011

Byung-Hoon Woo
Affiliation:
woo.b.aa@m.titech.ac.jp, Tokyo institute of technology, Precision and Intelligence Laboratory, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Tokyo, 226-8503, Japan
Masato Sone
Affiliation:
woo.b.aa@m.titech.ac.jp, Tokyo institute of technology, Precision and Intelligence Laboratory, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Tokyo, 226-8503, Japan
Akinobu Shibata
Affiliation:
woo.b.aa@m.titech.ac.jp, Tokyo institute of technology, Precision and Intelligence Laboratory, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Tokyo, 226-8503, Japan
Chiemi Ishiyama
Affiliation:
woo.b.aa@m.titech.ac.jp, Tokyo institute of technology, Precision and Intelligence Laboratory, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Tokyo, 226-8503, Japan
Masahiro Yamagata
Affiliation:
woo.b.aa@m.titech.ac.jp, Tokyo institute of technology, Precision and Intelligence Laboratory, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Tokyo, 226-8503, Japan
Kaoru Masuda
Affiliation:
woo.b.aa@m.titech.ac.jp, Tokyo institute of technology, Precision and Intelligence Laboratory, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Tokyo, 226-8503, Japan
Yakichi Higo
Affiliation:
woo.b.aa@m.titech.ac.jp, Tokyo institute of technology, Precision and Intelligence Laboratory, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Tokyo, 226-8503, Japan
Get access

Abstract

We propose a novel technique for electroless plating on polymer substrates using a dense CO2 beyond the critical point. Ni-P thin films were fabricated by a novel, hybrid technique consisting of two processes: catalyzation in supercritical CO2 with Pd bis-acetylacetonate and electroless plating in emulsion with dense carbon dioxide. Catalyzation in supercritical CO2 enabled the nucleation of a large number of Pd nuclei on a polyimide substrate without chemical pretreatment, and the deposition of a uniform Ni-P metal film. The electroless plating in emulsion with dense carbon dioxide produced a uniformly plated film without peeling or nodules. The improved uniformity was attained by the solubility and diffusivity of the dense CO2 beyond the critical point in the emulsion.

Type
Research Article
Copyright
Copyright © Materials Research Society 2008

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Varadan, V.K., Polymer MEMS and Nano- and Micro-Systems, John Wiley, (2003)Google Scholar
2. Bhaskaran, V., Hampden-Smith, M.J., Kodas, T.T., Chem. Vapor Deposit. 2, 85(1997).CrossRefGoogle Scholar
3. Yoshida, H., Sone, M., Mizushima, A., Yan, H., Wakabayashi, H., Abe, K., Tao, X. T., Ichihara, S., Miyata, S., Surf. Coat. Tech. 173, 285(2003).CrossRefGoogle Scholar
4. Miyamura, T., Koike, J., Mater. Sci. Eng. A 445–446, 620(2007).CrossRefGoogle Scholar
5. Reverchon, E., Adami, R, J. Supercrit. Fluids 37, 1(2006).CrossRefGoogle Scholar
6. Blackburn, J.M., Long, D.P., Cabanas, A., Watkins, J.J., Science 294, 141(2001).CrossRefGoogle Scholar
7. Uchiyama, H., Sone, M., Ishiyama, C., Endo, T., Hatsuzawa, T., Higo, Y.. J.Electrochem. Soc. 154, E91(2006).CrossRefGoogle Scholar

Save article to Kindle

To save this article to your Kindle, first ensure coreplatform@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about saving to your Kindle.

Note you can select to save to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Interface Stability between Ni-P film plated by Supercritical Electroless Plating and the Polymer Substrate
Available formats
×

Save article to Dropbox

To save this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you used this feature, you will be asked to authorise Cambridge Core to connect with your Dropbox account. Find out more about saving content to Dropbox.

Interface Stability between Ni-P film plated by Supercritical Electroless Plating and the Polymer Substrate
Available formats
×

Save article to Google Drive

To save this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you used this feature, you will be asked to authorise Cambridge Core to connect with your Google Drive account. Find out more about saving content to Google Drive.

Interface Stability between Ni-P film plated by Supercritical Electroless Plating and the Polymer Substrate
Available formats
×
×

Reply to: Submit a response

Please enter your response.

Your details

Please enter a valid email address.

Conflicting interests

Do you have any conflicting interests? *