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Film Formation Behavior of the Endohedral Metallofullerene DY@C82

Published online by Cambridge University Press:  10 February 2011

Houjin Huang  and
Shihe Yang
Houjin Huang
Affiliation:
Department of Chemistry, The Hong Kong University of Science and Technology Clear Water Bay, Kowloon, Hong Kong
Shihe Yang
Affiliation:
Department of Chemistry, The Hong Kong University of Science and Technology Clear Water Bay, Kowloon, Hong Kong
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Abstract

The Langmuir-Blodgett (LB) film formation behavior of the endohedral metallofullerene Dy@C82 was studied at the air/water and Ar/water interfaces. The LB film constructed at the Ar/water interface (2-4 layers) was found to be thinner and more uniform than at the air/water interface (4-6 layers). Particulate aggregates were observed in the LB films, which contrasts the extended wire networks formed by direct evaporation of the metallofullerene solution on a quartz plate. The UV-Vis absorption peaks are blue-shifted for the LB film deposited in air, which is attributed to the partial oxidation of the metallofullerene balls. They are red-shifted, however, for the LB film at the Ar/water interface presumably due to the interaction between the pristine metallofullerenes.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 593: Symposium U – Amorphous & Nanostructured Carbon , 1999 , 63
Copyright
Copyright © Materials Research Society 2000

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