Hostname: page-component-5c6d5d7d68-ckgrl Total loading time: 0 Render date: 2024-08-22T01:46:23.885Z Has data issue: false hasContentIssue false

Fast Changes in a-Si:H Solar Cells After Severe Light-Soaking

Published online by Cambridge University Press:  21 February 2011

Bolko Von Roedern*
Affiliation:
Solar Energy Research Institute, 1617 Cole Blvd, Golden, CO 80401–3993
Get access

Abstract

The fast changes observed in the stabilized state of a-Si:H solar cells and modules at temperatures below 70°C are inconsistent with the commonly accepted picture of “defect annealing.” The fast changes observed in the stabilized state, for example when the temperature is altered, are explained in terms of converting the charge state of the dangling bond defects that are already present in the material. It is suggested that the slow degradation of solar cells arises from the creation of new defects and can be described by fitting stretched exponential curves to the solar cell performance data.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Sandia National Laboratory, Report on Performance of Amorphous Silicon Photovoltaic Systems 1985 – 1989, SAND90–0612, UC–276, (1990).Google Scholar
2. B. von Roedern, to be published in Proceedings of the 10th European Photovoltaic Solar Energy Conference, Lisbon, April 8–12, 1991.Google Scholar
3. Palmer, R.G., Stein, D.L., Abrahams, E. and Anderson, P.W., Phys. Rev. Lett. 53, 958, (1984).Google Scholar
4. B. von Roedern, Mrig, L., Rummel, S., Waddington, D., Longrigg, P. and Luft, W., to be publishedGoogle Scholar
5. Pratt, G., to be published Proc. of PV AR&D Conference, Lakewood, CO, 1990, Solar Cells 30, (1991).Google Scholar
6. Park, H.R., Liu, J.Z., and Wagner, S., Appl. Phys. Lett. 55, 2658, (1989).Google Scholar
7. Crandall, R.S., Phys. Rev. B 43, 4057, (1991) provides an excellent review of these activation energies.CrossRefGoogle Scholar
8. McMahon, T.J., presented at this Conference, to be published this Volume.Google Scholar
9. Lee, C., Ohlsen, W.D., Taylor, P.C., Ullal, H.S. and Ceasar, G.P., Phys. Rev. B 31, 100, (1985).Google Scholar
10. Branz, H.M. and Silver, M., Phys. Rev. B 42, 7420, (1990), have indicated that defects or local potential fluctuations will cause a natural distribution between charged and neutral dangling bonds.Google Scholar
11. von Roedern, B., Int. Meeting on Stability of Amorphous Silicon Materials and Solar Cells, Denver, CO, 1991, to be published in American Institute of Physics Conference Proc.Google Scholar
12. Yamasaki, S., private communication.Google Scholar