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Energy Transfer Studies of Polyphenylene-Type Polymers to a Series of Dyes.

Published online by Cambridge University Press:  15 February 2011

Sean O. Clancy ,
Asanga B. Padmaperuma  and
Aaron W. Harper
Sean O. Clancy
Affiliation:
Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, University Park, 837 Bloom Walk, Los Angeles, California 90089-1661.
Asanga B. Padmaperuma
Affiliation:
Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, University Park, 837 Bloom Walk, Los Angeles, California 90089-1661.
Aaron W. Harper
Affiliation:
Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, University Park, 837 Bloom Walk, Los Angeles, California 90089-1661.
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Abstract

Energy transfer from two polyphenylene-type polymers to a series of organic dyes was studied. One of the polymers was synthesized via Suzuki coupling of 1,4-phenyldiboronic acid with 1,4-dibromobenzene to obtain polyphenylene. The other polymer was a polybenzophenone generated by a nickel-mediated coupling of 2,5-dichloro-4'-methylbenzophenone. These polymers were used as the energy donors. A variety of Coumarins and other dyes were used as acceptors. Photophysical data and energy transfer parameters were determined.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 771: Symposium L – Organic and Polymeric Materials and Devices , 2003 , L4.11
Copyright
Copyright © Materials Research Society 2003

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