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Energy Dependence of Defects in a-Si:H Solar Cells During Degradation and Annealing Processes

Published online by Cambridge University Press:  15 February 2011

Domenico Caputo
Affiliation:
Department of Electronic Engineering, via Eudossiana, 18 00184 Rome, (Italy)
Francesco Lemmi
Affiliation:
Department of Electronic Engineering, via Eudossiana, 18 00184 Rome, (Italy)
Fabrizio Palma
Affiliation:
Department of Electronic Engineering, via Eudossiana, 18 00184 Rome, (Italy)
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Abstract

In this work we report on the effect of current-induced degradation and annealing on p-i-n amorphous silicon solar cells. Current-voltage curves and capacitance measurements under forward bias have been used to monitor the current-induced changes as a function of time. We found that the recovery rate increases with the annealing current, while the stabilized value of efficiency decreases. Comparison of short circuit current and capacitance evolution suggests that defect kinetics in the electronic gap occurs in a different way during degradation and annealing. This behavior can be modeled assuming a faster annealing of defects closest to the extended band and a slower annealing of mid-gap defects.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

1. Staebler, D.L., Wronski, C.R., Appl. Phys. Lett., 31, 292, (1977).CrossRefGoogle Scholar
2. Stutzmann, M., Jackson, W.B., Tsai, C.C., Phys. Rev. B, 32, 23, (1985).CrossRefGoogle Scholar
3. Gleskova, H., Morin, P.A., Wagner, S., in Amorphous Silicon Technology edited by Schiff, E.A., Thompson, M.J., Madan, A., Tanaka, K., Le Comber, P.G., (Mater. Res. Soc. Proc, 297, Pittsburgh, PA, 1993) pp. 589.Google Scholar
4. Gleskova, H., Bullock, J.N., Wagner, S., J. Non-Crist. Solids, 164–166, 183, (1993).CrossRefGoogle Scholar
5. Hata, N., Wagner, S., J. Appl. Phys., 72, 2857, (1992).CrossRefGoogle Scholar
6. Caputo, D., Bullock, J., Gleskova, H., Wagner, S., MRS Symp. Proc., 336, 165, (1994).CrossRefGoogle Scholar
7. Cohen, J. D. in Semiconductor and Semimetals, edited by Academic Press, Inc(London, C, 1984) pp. 998.Google Scholar
8. Caputo, D., Palma, F., Physica Scripta, 53, 617, (1996).CrossRefGoogle Scholar
9. Caputo, D., Irrera, F., Palma, F., Tucci, M., Physica Scripta, 49, 724, (1994).CrossRefGoogle Scholar
10. Caputo, D., de Cesare, G., Ippolito, A., Irrera, F., Palma, F., Tucci, M., in 13th Photovoltaic Specialist European Conference, edited by Stephens, H.S. & Associates, , (Nice, 1995) pp. 171174.Google Scholar
11. Palma, F., Pastore, A., to be published in Physica Scripta.Google Scholar
12. Caputo, D., Forghieri, U., Palma, F., in 13th Photovoltaic Specialist European Conference. edited by Stephens, H.S. & Associates, , (Nice, 1995) pp. 187190.Google Scholar
13. Stutzmann, M., Phil. Mag. B, 56, 63, (1987).CrossRefGoogle Scholar
14. Adler, D., J. de Phys., 42–C4, 3, (1981).Google Scholar
15. Adler, D., Solar Cells, 9, 133, (1982).CrossRefGoogle Scholar